重氮化反应 氨基变硝基 1,4-DINITRONAPHTHALENE.pdfVIP

Organic Syntheses, Coll. Vol. 3, p.341 (1955); Vol. 28, p.52 (1948). 1,4-DINITRONAPHTHALENE [Naphthalene, 1,4-dinitro-] Submitted by H. H. Hodgson, A. P. Mahadevan, and E. R. Ward. Checked by C. C. Price and Sing-Tuh Voong. 1. Procedure Ten grams (0.14 mole) of powdered sodium nitrite is dissolved in 50 ml. of concentrated sulfuric acid (sp. gr. 1.84) contained in a 1-l. beaker placed in an ice bath. A solution