Bis(trifluoromethyl)-containing 1-azatricycloheptanes:(Bis(trifluoromethyl)包含1-azatricycloheptanes).pdfVIP
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I572 Russian Chemical Bulletin, Vol. 46, ,Vo. 9, September, 1997
Bis (trifluoromethyl)-containing 1-azatricyeloheptanes
1. Synthesis and hydrohaiogenation of
3 -halo- 7,7 - his (trifluoromethyl) - 1 -azatricyelo [2.2.1.0 z, 6] heptanes
V. M. Nagaev,* G..4. Sokolsky, S. S. Khokhlov, and .4. F. Yeleyev
State Scientific Center of the Russian Federation
State Scientific Research Institute of Organic Chemistry and Technology,
23 sh. Entuziaytov, 111024 Moscow, Russian Federation.
Fax: 007 (095) 273 1413
Methods for the synthesis of anti-3-halo-7,7-bis(trifluoromethyl)-l-azatricyc-
lo[2.2.1.02,6]heptanes by conjugated halogenation of 3,3-bis(trifluoromethyl)-2-azabicyc-
Io[2.2.1] hept-5-ene have been developed. Hydrohalogenafion of the Lynthesized 1-azatricyclic
compounds gives exclusively 6,7-dihalo-3,3-bis(trifluoromethyl)-2-azabicyclo[2.2. l]heptanes.
Key words: 2-azabicycloheptanes, conjugated halogenation; 1-azatrieycloheptanes.
hydrohalogenation; rearrangements; nonclassical cation.
In overcoming microorganism resistance with re- synthesizing them from bis(trifluoromethyl)-l-aza-
spect to existing microbicides, synthetic screening of tricyclo[2.2.t.02,6}heptanes. For instance (Scheme 1),
series of compounds with new types of structures is of one of th
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