宽谱带吸收纳米TiO2光催化剂的制备及催化活性研究-卫生毒理学专业论文.docxVIP

南华大学 南华大学硕士学位论文 宽谱带吸收纳米 TiO2 光催化剂的制备及催化活性研究 PAGE PAGE 3 光催化剂用量为4g·L-1，最佳反应时间为90min，加入H2O2最佳初始浓度为 4mmol·L-1。 结论： （1）采用共沉淀-浸渍法可制备宽谱带吸收的掺杂S的纳米S/TiO2光催化剂。 煅烧温度、煅烧时间、S元素掺杂浓度等因素对改性效果都有较大影响。纳米 S/TiO2在可见光下对亚甲基蓝的催化降解活性明显高于纯纳米TiO2。 （2）超声波对光催化降解反应有协同作用，US/VIS/S-TiO2 体系对 MB 的 降解效果比纯纳米 TiO2 降解效率提高约 5 倍。该反应体系降解时间短、降解效 率高、操作简单、成本低、具有可推广前景。 （3）US/VIS/S-TiO2体系的光催化活性受pH值、MB浓度、光催化剂用量、 光照时间及H2O2用量等因素的影响。 关键词：共沉淀-浸渍；掺杂；光反应器；超声；光降解；影响因素；亚甲 基蓝 ABSTRACT Preparation and Photocatalytic Reactivity of Ti02 Nanoparticles photochemical catalyst with broad band absorption Objective: Based on the research on modificated TiO2 nanoparticles photochemical catalyst，this thesis used the S doped TiO2 system as its research subject. Using the new synthesis method and marerial, it aimed to optimize the microsructure of TiO2 and study the photocatalytic degradation mechanism, to expand the band absorption area of photochemical catalyst and raise the catalytic activity in visible light. Besides, using the reaction of TiO2 nanoparticles photochemical catalyst with broad band absorption degradating the Methylene Blue (MB) as a model, this thesis studied the synergistic effects of ultrasound wave in photocatalytic degradation using visible light and the influence on the efficacy of by various experiment conditions, so as to provide the instructions for the research and application of photochemical catalyst with broad band absorption and provide the experimental basis for effective use of solar energy and degradation of azo organics. contents: (1）Synthesize the modificated TiO2 nanoparticles photochemical catalyst by coprecipitation-precipitation method. Analysis the characteristics of modificated TiO2 nanoparticles photochemical catalyst and mechanism of doping of catalyst by XRD, TEM, UV-Vis-DRs, and XPS. Study the using period of modificated TiO2 nanoparticles photochemical catalyst. Make the photocatalytic degradation reactor with effective catalytic activity and stability. (5) Optimize the reaction syst