养生健肝茶中重金属的溶出伏安法测定.pdf

养生健肝茶中重金属的溶出伏安法测定 摘 要 本文叙述了用汞膜电极阳极溶出伏安法的电化学测定保健茶中重金属的方 法。这项研究工作的目的在于使所有影响这个测定方法的因素向有利方向发展。 电压波形（线性扫描，微分脉冲，方波），扫描参数，富集时间，富集电压和表 面清理的过程的检测都对溶出的峰形，强度有影响。3种支持电解液（底液）已 经被测试过。用稀盐酸做支持电解液是得到最好的响应结果。用电化学和物理方 法清理表面，目的是清除汞膜电极表面沉积的待测元素，这是获得一个较好性能 的工作电极所必需的步骤。线性响应，再现性，精确性和检测限同样需要测评。 关键词：阳极溶出伏安法，金属离子，汞膜电极 I 养生健肝茶中重金属的溶出伏安法测定 Abstract The electrochemical determination of heavy metal by anodic stripping voltammetry (ASV) at a mercury film electrode is described. The aim of this work is to optimise all factors that can influence this determination. Potential wave forms (linear sweep, differential pulse, square wave),potential scan parameters, deposition time, deposition potential and surface cleaning procedures were examined for their effect on the mercury peak shape and intensity. Three supporting electrolytes were tested. The best responses were obtained with square wave potential wave form and diluted HCl as supporting electrolyte. Electrochemical and mechanical surface cleaning, aimed at removing the amount of deposited onto the Hg surface, were necessary for obtaining a good performance of the electrode. Response linearity, repeatability, accuracy and detection limit were also evaluated. Key words: anodic stripping voltammetry, mercury film electrode, metallic ion II 养生健肝茶中重金属的溶出伏安法测定 目 录 第一章 前 言 1 1.1茶叶中重金属的测定方法1 1.2重金属元素对人体的影响2 第二章 文献综述 4 2.1电化学分析方法简介4 2.2伏安法原理5 2.3 电位溶出法的特点8 第三章 实验准备9 3.1 仪器和试剂 9 3.1.1 仪器9 3.1.2 试剂9 3.2实验准备10 3.2.1样品溶液的配制 10 3.2