超临界CO2条件下钢的腐蚀行为研究现状.docVIP

超临界CO2条件下钢的腐蚀行为研究 张玉，庞晓露，高克玮 2011-04-16；修订日期：2011-05-29 联系人：高克玮，教授，kwgao@mater.ustb.edu.cn （北京科技大学材料物理与化学系北京100083 摘 要：低压CO2腐蚀规律已经被人们广泛认识，而超临界CO2腐蚀方面的研究非常有限。目前国内外科研者主要研究了钢在超临界CO2环境中的腐蚀速率、腐蚀产物膜的结构、形貌及组成以及电化学行为等，发现超临界CO2含水环境中碳钢的腐蚀非常严重，13Cr 不锈钢以及高合金CrNi不锈钢缓蚀剂能够降低碳钢及不锈钢的腐蚀速率，但目前所测的缓蚀剂都不能将碳钢的腐蚀速率降到可以接受的值；超临界CO2中含有O2、SO2、NO2等气体杂质及它们的混合物时，碳钢的腐蚀速率增加。然而，现有的研究中都没有涉及到超临界CO2腐蚀机理问题关键词：碳钢；不锈钢；超临界CO2；腐蚀；缓蚀剂 A Review on Corrosion Behaviors of Steels under Supercritical CO2 Conditions , QU Shao-peng, PANG Xiao-lu, GAO Ke-wei (Department of Materials Physics and Chemistry University of Science and Technology Beijing, Beijing 100083, China) Abstract：CO2 corrosion at low partial pressure has been widely recognized, but the researches on supercritical carbon dioxide (SC CO2) corrosion were very limited. By far, investigations on steel corrosion under SC CO2 conditions were mainly on the corrosion rate, the structure, morphology and composition of corrosion scales, and the electrochemical behaviors. It was found that in aqueous SC CO2 environment, the corrosion rate of carbon steel was very high, even 13Cr steel and high alloy CrNi stainless steel were also subjected to a bit of corrosion; inhibitor can reduce the corrosion rate of carbon steels and stainless steels, but none of the tested inhibitors can reduce the corrosion rate of carbon steel to the acceptable value; impurities such as O2, SO2, NO2 and their mixtures in SC CO2 increased the corrosion rate of carbon steel. However, present studies were not related to the corrosion mechanism in SC CO2. This paper reviews the research results on corrosion behaviors of steel under supercritical CO2 conditions, points out the shortcomings in the present investigations and finally looks forward to the research prospects on supercritical CO2 corrosion. It is expected that this paper can not only provide reference for the scientist in the field of supercritical CO2 corrosion, but also be served as a theoretical guidance for materials selecti