离子色谱-电感耦合等离子体质谱法检测玩具中六价铬.pdfVIP

2013 年第 5 期 Vol.23 No. 5 检验检疫学刊 JOURNAL OF INSPECTION AND QUARANTINE 离子色谱-电感耦合等离子体质谱法检测玩具中六价铬 * 洪锦清 陈 明 李 敬 程玉龙 王 瓒 （江苏出入境检验检疫局 江苏扬州 225009) 摘要摘要 建立了用离子色谱- 电感耦合等离子体质谱法检测玩具材料迁移液中六价铬的新方法。采用阴离子 交换色谱柱、中性NH NO 淋洗液，结合梯度洗脱和碰撞反应池技术。实验表明，本方法可以很好地分离溶液 4 3 中的三价铬和六价铬。当进样量为100 μL 时，对溶液中六价铬的检出限达到0.02 μg/L 。本方法灵敏度高，线 性范围宽，加标回收率接近100%，能够满足新指令对玩具材料中可迁移六价铬的检测要求。 关键词关键词 六价铬；玩具；离子色谱；电感耦合等离子体质谱 中图分类号中图分类号 O657.63 Determination of Chromium (VI) in Toys Using Ion Chromatography-Inductively Coupled Plasma Mass Spectrometry * Hong Jinqing, Chen Ming , Li Jing, Cheng Yulong, Wang Zan (Jiangsu Entry-Exit Inspection and Quarantine Bureau, Yangzhou, Jiangsu, 225009) Abstract: To cope with the new EU toy safety directive, we developed a new method based on ion chromatography combined with inductively coupled plasma mass spectrometry (IC-ICP-MS) to measure chromium (VI) in the migration solution of toy materials. This method engaged IonPac AG11 anion-exchange column and neutral NH NO 4 3 mobile phase, with gradient elution and collision cell technology. The results showed that chromium (III) and chromium (VI) could be separated very well. A limit of detection of 0.02 μg/L for chromium (VI) was obtained with an injection volume of 100 μL. This method is of high sensitivity, wide linearity range, and good recovery rate (approaching 100 %), which can meet the requirements of new directive for determination of migratable chromium (VI) in toy materials. Key Words: Chromium (VI);