树脂含量对改质沥青焦微观结构和电化学性能影响研究.pdfVIP

树脂含量对改质沥青焦微观结构和电化学性能影响的研究 1 2 2 1 1 李新禄 胡成秋 沈万慈 康飞宇 清华大学 材料系 北京 100084 鞍山热能研究院 辽宁 鞍山 114004 摘要 以煤沥青为原料 通过改变原料沥青中 树脂的含量和调控热处理工艺 以提高沥青焦的可石墨化程度 考察 树脂的不同含量对沥青焦的微观结构及嵌 锂行为的影响 改质沥青焦的d002 由0.34639nm 降至0.34547nm Lc 由5.6761nm 升至 6.1049nm 在扣式锂离子电池中 将所得的沥青焦制作成负极 采用金属 锂为对电极 电解液为1mol/L 的LiPF +EC/DEC(1:1)在0.5mA 的充放电电流下 6 沥青焦的放电容量从改质前的208.1mAh/g 增加到改质后的242.8 mAh/g 首次循 环效率从80.3%提高到86.3% 综合考察放电容量和循环效率等指标 流线型结 构的沥青焦优于镶嵌型结构 关键词 改质沥青焦 可石墨化程度 显微结构 电化学性能 An invetigation on the influence of -resin contents on the microstructure and electrochemical properties of modified pitch coke LI Xin-lu 1 2, HU Cheng-qiu 2 , KANG Fei-yu 1, SHEN Wan-ci 1 (1. Department of Materials Science and Engineering, Tsinghua University, Beijing 100084; 2. Anshan Research Institute of Thermo-Energy, Anshan, Liaoning 114004) Abstract: The -resin contents in the raw coal tar pitch were changed and the heat-treatment process was controlled in order to improve the graphizability of pitch coke. The influences of the -resin contents on the microstructure and the electrochemical properties of pitch coke were investigated. The results showed that its microstructure was modified, d002 decreased from 0.34639nm to 0.34575nm while Lc increased from 5.6761nm to 6.1049nm. In the lithium ion battery, the modified pitch coke was used as the anode material, the metal lithium was used as the opposite electrode, 1mol/L LiPF6+EC/DEC (1:1) was adopted as the electrolyte. At the 0.5mA charge-discharge current, the discharge capacity of the modified pitch coke increased from 208.1mAh/g to 242.8 mAh/g, and the first cycle efficiency increased from 80.3% to 86.3%