炔丙基萘酰亚胺的合成、表征和晶体结构.pdfVIP

炔丙基萘酰亚胺的合成、表征和晶体结构.pdf

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中国科技论文在线 Synthesis, Characterization, and Crystal Structures of Propargyl Naphthalimides# ** 5 PENG Li-Ping, LV Jing-Song, ZHOU Cheng-He (School of Chemistry and Chemical Engineering, Southwest University, Chongqing, 400715) Abstract: Two title molecules, 6-bromo-2-(prop-2-ynylamino)-1H-benzo[de]isoquinoline -1,3(2H)-dione (4) and 6-bromo-2-(diprop-2-ynylamino)-1H-benzo[de]isoquinoline-1,3(2H)-dione (5), were synthesized and characterized by single-crystal X-ray diffraction, IR, 1H NMR, MS, fluorescence 10 spectra, and powder X-ray diffraction (PXRD). The structure of crystal 4 (CCDC 981232) belongs to the triclinic system, space group P-1 with a = 7.5827(5), b = 7.8886(6), c = 10.5217(7) Å, α = 96.368(6), β = 90.223(5), γ = 92.353(6)º, V = 624.95(7) Å3, Dc = 1.749 g/cm3, μ = 4.52 mm-1, F(000) = 328, Rint = 0.0260, R (I > 2σ(I)) = 0.0622, wR (I > 2σ(I)) = 0.1454, R (all data) = 0.0683 and wR (all data) = 0.1484. In this crystal, a 2D layer supramolecular network structure was formed through 15 hydrogen bonds of N(2)−H(2)•••O(1) and C(15)−H(15)•••O(1), and the Br atom was disordered over two positions with refined occupancies of 0.8589(3) and 0. 1410(7). The calculated bond lengths and bond angles of compound 4 were consistent with the result of crystallography. Fluorescence properties of compounds 4 and 5 in different solvents were also studied. Moreover, the two synthesized compounds 4 and 5 were screened for their antimicrobial activities against

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