Zr_xCe_1_x_O_2催化剂催化湿式氧化乙酸的活性研究.pdfVIP

2006 64 Vol. 64, 2006 15 , ACTA CHIMICA SINICA No. 15, · · Zr Ce O x 1 x 2 * ( 100084) Zr Ce O , BET, XRD XPS , x 1 x 2 . : Zr Ce 1 9 , (COD)5000 mg/L, 230 , 5 MPa , 120 min , COD 76% . CeO Zr , HO • , 2 2 . ; ; Zr Ce O ; x 1 x 2 Study on Catalytic Wet Air Oxidation of Acetic Acid by Zr Ce O Catalyst x 1 x 2 WANG, Jian-Bing* ZHU, Wan-Peng YANG, Shao-Xia ZHOU, Yun-Rui (Department of Environmental Science and Engineering, Tsinghua University, Beijing 100084) Abstract A series of Zr Ce O catalysts were prepared by co-precipitation. They were characterized by x 1 x 2 BET, XRD and XPS. The catalytic wet air oxidation of acetic acid was carried out with these catalysts. It showed that the Zr Ce O catalyst with 1 9 atomic ratio of zirconium to cerium demonstrated the best ac- x 1 x 2 tivity. At initial chemical oxygen demand (COD) of 5000 mg/L, reaction temperature of 230 and the pressure of 5 MPa, the removal efficiency of COD was 76% after 120 min. The good activity of this catalyst could be due to adding zirconium into CeO2 which could increas