铕--芳香羧酸--丁二酸三元配合物的合成及荧光性能研究.pdfVIP

23 3 Vol.23 No.3 2 0 0 9 6 CHINESE JOURNAL OF MATERIALS RESEARCH June 2 0 0 9 – – ∗ ( 410082) , . ÆEDTA ÆÆÆ ; Æ; Æ. . , , , , , O614 1005-3093(2009)03-0257-07 Synthesis and fluorescent properties of the ternary complexes of europium with aromatic carboxylic acid and butanedioic acid GOU Lining ZHOU Yue TAN Hui WANG Liying LI Pingliang GUO Dongcai∗∗ (School of Chemistry and Chemical Engineering, Hunan University, Changsha 410082) * Supported by Natural Science Foundation of Hunan Province No.05JJ30020 and the Development Foun- dation of the Scientific and Technological Bureau of Hunan Province No.04GK3035. Manuscript received September 27, 2008; in revised form February 13, 2009. ** To whom correspondence should be addressed, Tel:(0731)8821449, E-mail: dcguo2001@163.com ABSTRACT Six new ternary complexes of europium were synthesized with the first ligands of benzoic acid, p-methylbenzoic acid, m-chlorobenzoic acid, p-chlorobenzoic acid, p-hydroxylbenzoic acid, methoxy- benzoic acid and the second ligand of butanedioic acid. Their molecular composition and structures were characterized by means of elemental analysis, EDTA titrimetric method, FT–IR and UV spectroscopies. The thermal stability properties of the title complexes were studied by thermal analysis instrument. The luminescent properties of the title complexes and their corresponding binary complexes were investigated by means of fluorescence instrument. The fluorescence spectra data show that the new ternary complexes have much higher luminescence intensity than their corresponding binary complexes. KEY WORDS organic poly