_碱_矿渣_粉煤灰_偏高岭土_水合陶瓷产物组成和微观结构.pdfVIP

39 3 Vol. 39 No. 3 2 0 1 1 3 JOURNAL OF THE CHINESE CERAMIC SOCIETY March 2011 ––– 1,2,3 2 2 2 2 3 (1. 621010 2. 621010 3. () 430074) X ––– ––– n(Si):n(Al):n(Na) 90180 180 Si Al Si Al 2.0 TQ170.7 TQ177 A 0454–5648(2011)03–0512–06 Composition and Microstructure of “Alkali–Slag–Coal Fly Ash–Metakaolin” Hydroceramics WANG Jin1,2,3 2 2 2 2 3 HAN Chaojiang WANG Junxia LI Yuxiang TENG Yuancheng WU Xiuling (1. National Defense Key Discipline Lab of Nuclear Waste and Environment Safety, Southwest University of Science and Technology, Mianyang 621010, Sichuan; 2. School of Materials Science and Engineering, Southwest University of Science and Technology, Mianyang 621010, Sichuan; 3. Faculty of Materials Science and Chemical Engineering, Engineering Research Center of Nano-Geomaterials of Ministry of Education, China University of Geosciences, Wuhan 430074, China) Abstract: The composition and microstructure of hydration products of “alkali–slag–coal fly ash–metakaolin” hydroceramics based solidification materials for nuclear wastes were investigated by X-ray diffraction and scanning electron microscope. The hydration and forming mechanism of the hydroceramics were discussed. The results show that the composition of “alkali–slag–coal fly ash– metakaolin” hydroceramics is correlated to some factors such as synthesis temperature, hydrothermal reaction time, n(Si):n(Al):n(Na) and dosage of alkali activator agent. The increase of temperature and reaction time can favor the formation of zeolite crystal phase in a temperature range of 90–180 . At 180 , it can be more effective to form a