李明春——高分子量丙烯酸酯共聚物的制备及表征.docxVIP

高分子量丙烯酸酯共聚物的制备及表征方江海，辛梅华，李明春*，姚文杰，张艺（华侨大学材料科学与工程学院，环境友好功能材料教育部工程中心，福建厦门 361021）摘 要：以丙烯酸丁酯、丙烯酸乙酯和丙烯腈为主要单体，甲基丙烯酸羟乙酯和甲基丙烯酸羟丙酯为功能单体，采用悬浮聚合法制备了高分子量和高转化率的丙烯酸酯共聚物。考察了引发剂种类和用量、聚合反应温度、分散剂类型和浓度以及介质pH值等因素对聚合反应转化率和聚合物分子量的影响，并用GPC、FTIR和TGA对产物进行表征。结果表明，选择0.66%的偶氮二异丁氰作引发剂，1.5%的自制无机-有机高分子（PVA混合物）作分散剂，pH7.5，65℃聚合反应6h，制得的共聚物重均分子量达6.86106，涂层抗渗水水柱高度超过2000mm，热分解温度为320℃，单体转化率98.11%，聚合反应稳定，产品性状好。关键词：丙烯酸酯共聚物；悬浮聚合；高分子量；转化率；抗渗水性中图分类号：TQ 325.7 文献标识码：A 文章编号：Synthesis and characterization of HMW acrylate copolymerFANG Jiang-hai, XIN Mei-hua, LI Ming-chun*,YAO Wen-jie, ZHANG Yi(College of Material Science and Engineering, Huaqiao University, Engineering Research Center of Environment-Friendly Functional Materials, Ministry of Education, Xiamen, Fujian 361021)Abstract: The acrylate copolymer of high molecular weight and high conversion rate was synthesized with butyl acrylate, ethyl acrylate and acrylonitrile as main monomers, hydroxyethyl methyacrylate and hydroxypropyl methyacrylate as functional monomers by suspension polymerization. The effects of the type and concentration of initiators, polymerization temperature, the kind and concentration of dispersing agents, and pH value on the final molecular weight of the copolymer and conversion rate of monomers were investigated. The final products were characterized by GPC, FTIR and TGA. The results showed that the weight-average molecular weight of copolymer could reach to 6.86106, the final conversion rate was 98.11%, the thermal decomposition temperature was above 320℃ and water colunm height was above 2000mm at following conditions, the amounts of initiator AIBN and homemade inorganic-organic macromolecular dispersing agent (PVA mixture) were 0.66% and 1.5% respectively, and the temperature and time of the suspension polymerization were 65℃and 6h under pH7.5 of reaction media. Key words: Arylate copolymer; suspension polymerization; high molecular weight; conversion rate；anti-static water-pressure丙烯酸树脂具有成膜性好、室温稳定性和加工性能优异等特性，可应用于许多工业领域，因此有关丙烯酸树