含卤素取代基四硫富瓦烯的合成与研究进展.pdfVIP

2009 年第 29 卷 有 机 化 学 Vol. 29, 2009 第 6 期, 858～866 Chinese Journal of Organic Chemistry No. 6, 858～866 ·综述与进展· 含卤素取代基四硫富瓦烯的合成与研究进展 李洪启*,a 宋燕西b 李秀梅c (a 东华大学化学化工与生物工程学院 上海 201620) (b 东华大学环境科学与工程学院 上海 201620) (c 内蒙古通辽职业学院理工系 通辽 028000) 摘要 简要概括了含卤素取代基四硫富瓦烯(TTF)衍生物的主要合成方法, 即 TTF 及其衍生物的直接卤化法以及卤代 1,3-二硫杂环戊烯-2-(硫)酮在亚磷酸三烷基酯参与下的偶合反应. 介绍了含卤素TTF 衍生物的电化学、结晶和成膜性能, 及其作为重要的合成中间体在构筑给体-受体二元体、低聚 TTF 体系、含 TTF 单元的环蕃、含 TTF 单元的聚合物以及 各种官能化 TTF 衍生物中的应用. 提出了含卤素 TTF 衍生物的研究发展趋势. 关键词 四硫富瓦烯; 卤素取代基; 合成; 电化学性能; 合成中间体 Advances in Synthesis and Research of Tetrathiafulvalenes Containing Halogen Substituent Li, Hongqi*,a Song, Yanxib Li, Xiumeic (a College of Chemistry, Chemical Engineering and Biotechnology, Donghua University , Shanghai 201620) (b College of Environmental Science and Engineering, Donghua University, Shanghai 201620) (c Department of Physics and Technology , Inner Mongolia Tongliao Vocational College , Tongliao 028000) Abstract The two main methods for the synthesis of tetrathiafulvalene (TTF) derivatives containing halogen substituent, namely the direct halogenation of TTF and its derivatives and the trialkyl phosphite-mediated coupling of halogenated 1,3-dithiole-2-thione (or 2-one) compounds are outlined briefly. Electrochemical, crystalline, and film-forming properties as well as applications to construction of do- nor-acceptor dyads, oligomeric TTF systems, TTF-containing cyclophanes