2_羟基_1_萘醛缩2_氨基_4_甲基吡啶的合成及其热色性研究_朱少萍.pdfVIP

38 11 Vo l38 No11 2010 11 N EW CH EM ICAL M A T E RIA L S 81 2--1-2- -4- 1 2 1 1 1 朱少萍 冯玉英 乐传俊 杨 梅 高振兴 ( 1 常州工学院理学院, 常州21300 2; 2 南京师范大学分析测试中心, 南京210097) 成出含杂环的席夫碱类化 物2- 羟基- 1- 萘醛缩2- 氨基- 4- 甲基吡啶, 通过元素分析核磁共振氢谱红外 光谱等表征了其结构借助差示扫描量热技术原位升温红外紫外- 可见吸收光谱等研究了其热色性能, 探讨了变色的 机理, 并对变色前后以及恢复原色后的化 物的结构之间的关系进行了研究, 此外标题化 物在甲苯溶液中也显示出热 色性结果表明: 此类席夫碱是由于邻羟基的存在而导致热色性, 恢复原色后与原化 物的结构一致, 这也是其热色性具 有高重复性的原因 杂环席夫碱, 成, 互变异构, 可逆热色性 Study on synthesis and thermochromic properties of 2-N-(2- hydroxyl-naphthaldehyde)-imino-4-methyl-pyridine 1 2 1 1 1 Zhu Sh aoping Feng Y uying Y ue Chu anjun Y ang M ei Gao Zhenx ing ( 1 Schoo l of Science, Changzhou In st it ut e of T echnolog y, Ch ang zhou 213002; ( 2 A naly sis and T est ing Cent er, N anjing N o rmal U niv ersity , N anjing 210097) Abstract A no vel Shif f b ase 2- N- ( 2- hy drox y-l naphth aldehyde)- im ino- 4- m ethyl- pyr idine h as been synthesized T he title co mpo und h as been ch aracter ized by elem ental analysis, 1 H- N M R, and IR spectr a T he ther mochro m ic pro p er ties has been studied by DSC analysis, in situ elev ated temper ature IR and U V- V isible spectr a T he r esult s show ed th at the rever s- ible thermochro m ism ow ing to the rever sible tautom er ism of eno-l im ine and ket o- am ine f or m s Key words Schiff base of hetero cycle, sy nthesis, tauto m erism , rev er sible ther