前驱液离子浓度对CoAl2O4天蓝纳米陶瓷颜料结构与性能影响的研究.pdfVIP

前驱液离子浓度对CoAl204天蓝纳米陶瓷颜料结构及性能影响的研究 张新河黄剑锋1朱振峰邓飞 (陕西科技大学材料科学与工程学院，陕西咸阳，712081) 通过XRD、TEM和颜色测定等对制备的纳米颜料进行了表征，重点研究了增溶离子浓度对CoAl204 纳米晶结构及性能的影响。结果表明，随前驱离子浓度增加，纳米晶的尺寸有所减小，团聚现象有所 增加，颜料的色饱和度增加，主波长减小，明度出现极值。 关键词：微乳液；前驱液离子浓度；CoAl204陶瓷颜料；纳米晶 Influenceofinitialionconcentrationonthestructure of and blue propertiesnano·COAl204pigment Xin—he Zhu DenFei Zhang HuangJian—fen91 Zhen—feng blue were a microemulsionwith Abstract：Nano—COAl204pigments by prepared process blue werecharacterized Span80一Tween60／hexanol／benzine byXRD，TEM system．Theas-preparedpigments andcolormeasurement．Theinfluenceofinitialionconcentrationonthestructureand ofnano— properties blue was resultsshowedthatwiththeincreaseoftheinitialion COAl204pigmentspecial investigated．The sizeof decreasedbutthe increased．In the concentration，the addition，with nano—particle agglomeration ion ofthe increaseoftheinitial colorimetricsaturation increasedandthe concentration，the pigment the ofthe aminimumvalueat decreased，while wavelength brightnesspigmentappeared the[Co“]is 8Wt％． solutionion ceramics concentration；CoAl204 Keyword：microemulsion；initial 前言 极强的呈色能力和优异的耐光性、耐侯性及耐化学品性，耐热性可达1200℃而在陶瓷装饰领域中得 到广泛应用…，根据合成的条件不同，CoAl204钴蓝陶