新一代功能性聚丙烯催化剂的研发进展.pdfVIP

116 PETROCHEM ICA L TECHNOLOGY 20 10 39 2 董金勇, 牛 慧 ( , 100190) [] , M gC l Z ieg ler- N atta, 2 , Z iegler- N atta/ () , , / , Z ieg ler- N atta / () , Z ieg ler- N atta / () [] ; Z ieg ler- N atta; ; ; [] 1000- 8144 ( 2010) 02 - 0116- 09 [ ] TQ 052 [] A R esearch and Development ofN ewGeneration FunctionalZieglerNatta Catalysts for Propylene Polymerization D ong Jin ong, N iu Hui (K e L aborator of Eng ineering Plastics, In stitute of Chem istr , Ch inese A cadem of Sc iences, B eijing 100190, Ch ina) [A stract] The future developm ent of Z ieglerN atta catal sts for prop lene pol m erization is discussed, of w h ich the tactful incorporation of singlesite catal sts( SSC s, includ ing both m etallocene and nonm etallocene t pes) w ith stateoftheart M gCl supported Z ielgerNatta catal sts to form 2 Z ieglerN atta/SSC h brid catal sts is deemed to represent a leading trend. Th is lies in the fact that SSC s are of versatile et defined catal tic properties for o lefin pol m erization, and their being incorporated w il,l in a controllab le w a , mi prove the copol m erization capab ilities of Z ieg lerNatta catal sts and give rise to new generation functional Z ieglerN atta catal sts capab le of producing high perform ance iPP( PP: pol prop lene) . Som e w elldesigned and prepared Z ieglerN atta/SSC h brid catal sts w ith specific catal tic functions have been tested in prop lene po l mer ization, w here the successful preparations of PP /EP( E: eth lene; P: prop lene) heterogeneous copol m ers and h igh m eltstrength PP validate the rationalit