形态控制技术探究新进展.pdfVIP

形态控制技术研究新进展 1 2 申开智 李又兵 （1.四川大学高分子科学与工程学院，高分子材料工程国家重点实验室，成都 四川 6100654； 2.重庆工学院材料科学与工程学院，重庆 400050） 摘要: 研制出新型的聚合物注射成型装置和挤出成型装置，创造性地在成型过程 中向成型设备或模具分别输入具有不同振频和振幅的振动场、不同拉伸比的拉伸 应力场、不同剪切速率的剪应力场、以及先剪切后拉伸的复合应力场等。按预期 目标成功地改变了聚合物凝聚态结构；改变了结晶聚合物的结晶度、取向度、晶 粒尺寸、晶胞参数（晶型）；生成了不同的串晶结构、串晶互锁结构。分别得到 了具有突出高强度、高模量的试样；自增强同时又自增韧的试样；在单方向应力 场中获得双向自增强结构的试样；以及在极少量高分子组分诱导下性能大幅度提 高的试样。上述研究工作都极富有创新性，在材料性能上都有所突破，研究工作 将高分子物理研究由静态引向了动态，为高分子工程研究提供了新思路，且具有 良好的应用前景。 关键词：形态控制，自增强，自增韧 New Progress of Morphology Control Technology 1 2 Shen Kaizhi Li Youbing (College of Polymer Science and Engineering, The State Key Laboratory of Polymer Materials Engineering, Sichuan University, Chengdu, Sichuan 610065; School of Material Science and Engineering, Chongqing Institute of Technology, Chongqing 400050.) ABSTRACT: New injection molding devices and extrusion devices were researched and developed in latest decade years. Versatile stress fields were introduced into processing devices and/ or mould during the procedure, such as vibration field with different vibration frequency and amplitude, stretching field with different drawing ratios, shearing field, first-shear-then-draw field, and so on. Alike prospective goal, the different superposed stress fields influence the polymer aggregation, crystallinity, degree of chain orientation, dimensions of crystalline and crystalline parameters with different shish-kebab structures and interlocking shish-kebab structures, resulting in prominent high strength and high modulus specimens, self-reinforcing and self-toughening injection molding simultaneously, self-reinforced specimens along double directions prepared via single stress field, and a few high molecular chain induced high performance extrusions. It is obvious that the ab