离子液体的物性与其在Nafion膜中的应用研究.pdfVIP

离子液体的物性及其在Nafion 膜中的应用研究 马院红 余兆祥 同济大学化学系，上海 200092 摘要：离子液体具有一系列优良性能。本文主要研究了[BMIm]BF 和[EMIm]BF 两种离子 4 4 液体的电化学稳定性；研究了它们的粘度与温度的关系、电导率与温度的关系以及电导率 与粘度之间的关系。研究发现[BMIm]BF4 的电化学窗口在4.0 V 以上，而[EMIm]BF4 的电 化学窗口在2.0 V 左右，说明[BMIm]BF 的电化学稳定性优于[EMIm]BF ；通过数值拟合 4 4 发现两种离子液体的电导率与温度之间满足Arrhenius 方程，电导率与粘度之间满足Walden 规则。此外，还将这两种离子液体负载到Nafion 膜上，研究了离子液体对Nafion 膜性能 的影响。 关键词：离子液体；Nafion 膜 中图分类号：O621.21 文献标志码：A Physical characteristics of ionic liquid and application in the Nafion membrane Ma Yuanhong Yu Zhaoxiang Chemistry Department of Tongji University, Shanghai, 20009 China Abstract: Ionic liquid has a series of unique characteristics. Electrochemical properties of two kinds of ionic liquids, 1-n-butyl-3-methyl imidazolium tetrafluoroborate ([BMIm]BF4) and 1-ethyl-3-methyl imidazolium tetrafluoroborate ([EMIm]BF ), were studied in this article. And 4 the relationships between viscosity and temperature, conductivity and temperature, conductivity and viscosity, were investigated too. The result shows the electrochemical window of [BMIm]BF4 is above 4.0V, but the one of [EMIm]BF4 is about 2.0V, that indicates that [BMIm]BF is more stable than [EMIm]BF . With the Numerical Method, I found that the 4 4 relationships between conductivity and temperature can be described by the Arrhenius Equation, and the relationships between conductivity and viscosity can be described by the Walden Law. In addition, these two kinds of ionic liquids were imb