改性凹凸棒石粘土吸附性能对比实验研究.pdfVIP

2000 年 4 月 工业水处理 Apr. ,2000 　　　　　　　　　　 　　　　　　　　　　　 第 20 卷第 4 期 Industrial Water Treatment Vol. 20 No. 4 改性凹凸棒石粘土吸附性能对比实验研究 ( ) 合肥工业大学资源与环境科学系 安徽合肥 ,230009 　　陈天虎 　　[摘要] 选用有代表性的染料和酚两类性质不同的污染物质为吸附质 ,凹凸棒石粘土和各种方法改性的凹凸棒 石粘土为吸附剂进行了吸附对比实验研究。实验发现用 1 M 磷酸改性能大幅度提高凹凸棒石粘土对染料和酚等 污染物的吸附能力。并且认为凹凸棒石粘土的吸附属于外表面吸附 —胶体和离子交换吸附 ,改性作用提高凹凸棒 石粘土吸附性能的机理是改性加工改变了凹凸棒石粘土中粘土颗粒的结构电荷和表面电荷及吸附活性。 　　[ 关键词] 凹凸棒石粘土;吸附 ;废水 ;染料 ;酚 ( ) 　　[ 中图分类号] TQ42424 　[文献标识码] A 　[文章编号] 1005 - 829X 2000 04 - 0027 - 03 Experimental study by contra st on the adsorbing capability of modified palygorskite clay CHEN Tianhu ( ) Depart ment of Resources and Envi ronment Hef ei U niversity of Technology , Hef ei 230009 , China Abstract : The adsorbing capabilit y of dye and hydroxybenzene is compared by palygorskite clay and various mod ified palygorskite clay. It is found that adsorbing capabilit y of dye and hydroxybenzene may be improved largely by palygorskite clay which is modified with 1 M phosphoric acid. it is thought that the adsorption of palygorskite clay is outersurface adsorptioncolloid and ion exchange adsorpsion. the mechanism of the modification which improves the adsorbing capacit y of palygorskite clay is that the structural electric charge and surface electric charge of the clay granules in palygorskite and adsorbing activity are modified. Key words :palygorskite clay ; adsorption ; wastewater ; dye ; phenol 　　凹凸棒石是含水富镁硅酸盐粘土矿