化学技术—运用红外线分析构建磷灰石超分子模型.pdfVIP

Hans Journal of Chemical Engineering and Technology 化学工程与技术, 2012, 2, 13-16 doi:10.4236/hjcet.2012.22003 Published Online April 2012 (/journal/hjcet) Establishing an Apatite Supramolecular Model with Fourier Transform Infrared Spectroscopy Assay ——Apatite Supramolecular Model 1 2 3* 3 Ming-Han Wu , Min-Hsi Wu , Cheng-Chei Wu , Su-Mei Mao 1Information Management, Tatung University, Taipei 2Graduate Institute of Chinese Medicine, Shanghai University of Chinese Medicine, Shanghai 3Biomaterial Research Center, George Dental Clinic, Taipei * Email: alen914@ Received: Jan. 11th, 2012; revised: Feb. 2nd, 2012; accepted: Feb. 4th, 2012 Abstract: The fluoridated hydroxyapatite (FHA) was used to enhance the anti-carious effect of human tooth. Both the treatment method and the optimizing molar ratio were naturally the key of the sintering effect. In current studies, we have investigated the molecular characteristics and the sintering mechanism of sintered FHA composites based on HA-CaF2 system. The molecular characteristics of the FHA composites assayed by Fourier transform infrared spectros- copy (FT-IR) techniques. The FHA composites were prepared by sintering different combinations of HA and CaF2 . FHA composites show the OH F HO and/or the OH F hydrogen absorption band under the FT-IR analysis. With grad-    ual increase of CaF2 content, the sequence of FT-IR bands show OH F stretching mode vibration first, then followed by OH F HO liberational mode vibration and, finally, the OH F