含氟水性聚氨酯分散体的合成.pdfVIP

第34 卷 第3 期 中 国 皮 革 Vol. 34 No. 3 2005 年2 月 CHINA LEATHER Feb.2005 Synthesis of aqueous fluorine- containing polyurethane 1, 3 1 1 2 2 陈建兵 王宇 王爱东 王武生 曾俊 1安徽大学化工学院, 合肥230039; 2安徽大学皮革化工研究中心, 合肥230039; 3池州师专, 池州247100 1, 3 1 1 2 2 Chen Jianbing , Wang Yu , Wang A idong , Wang Wusheng , Zeng Jun 1. College of Chemistry, Anhui University, Hefei 230039; 2.Research Center of Leather Chemicals, Anhui University, Hefei 230039; 3. Chemistry epartment of Chizhou College, Chizhou 247100 用巯基乙醇作为链转移剂,将甲基丙烯酸十二氟庚酯与丙烯酸酯共聚成端羟基大分子单 , 再合成到水性聚 氨酯上获得含氟聚氨酯分散 讨论了引发剂单 浓度及组成对端羟基含氟丙烯酸酯类共聚反应的影响, 并用表面红外证实了氟在聚合物膜表面的富集而赋予材料的拒水特征 氟 水性聚氨酯 分散 合成 TQ63 A Abstract A hydroxylterminal fluorinecontaining macromonomer was synthesized by radical co olymerization of dodecaflu orohe tyl methacrylate and butyl acrylatew ith merca toethanol as chaintransfer agent. An ionic aqueous fluorine containing olyurethane was obtained by condensation olymerization of the macromonomer, olyether hydro hilic comonomer and IPDI. The olymer films w ere studied by IR and ATR. Study shows that the fluorine grou s were enriched in the film surface. Keywords fluorine aqueous olyurethane dis ersion synthesis ; 11 CF 3 2 6mJ/ m , [ 2- 4] AIBN , , [ 1- 6] , , ; IP DI Mn 2 000 , , N- , , , ; Nilcot nexus- 870 IR , 12 [7- 11] [ 1] 121 , ; , 1 , : , , 1980 , 45 化工材 中 国 皮 革 第34 卷 , , , , , 10h, 45% , N , , , , , 2 1 Mn 2 000 N- , , 6h , , , , , , 122 : , , , , 222 , , : , , IR KBr , , , , ATR , 1!1 , 2 , , , 21 1 2 , , , [ 14] 23 AT R [ 15- 17] 1 , 2 500~ 2 590cm- 1 S- H , , 681cm- 1 550~ 705cm- 1, - S- C- S- C , S- H , S - C , 3 491cm- 1 3 450~ 3 200cm- 1, - O- H - OH, 1 680~ 1 620cm- 1 - C 式1 C- , 22 : , 2 1 [ 7- 13] , AIBN , 70 05!1 1!1 15!1 2!1 , AIBN , [12] 5 000 2 500 1 500 1 000 , / % 7272 8750 9585 9762 , 1 2 221 / % 10 30 50 70 90 100 1!5!4 2!5!3 3!5!2 4!5!1 5!5 1 , / % 60 95 96 84 75 94 46 第3 期