液体连续相撞击流强化过程特性及相关技术装备研发和应用.pdfVIP

液体连续相撞击流强化过程特性及相关 技术装备的研发和应用*1 *2 伍 沅 周玉新 郭 嘉 袁 军 武汉工程大学化工与制药学院/教育部暨湖北省绿色化工过程重点实验室 湖北 武汉 430073 摘要 液体连续相撞击流(LIS)具有高效微观混合、强烈压力波动和促进过程动力学等对分子尺度过程极有价 值的性质。在浸没循环撞击流反应器(SCISR)中深入研究了这些性质及其规律；进行了反应— 沉淀法制取多 种 “超细”和纳米材料的实验研究，制得粒径更细小、分布更窄、形貌可控的超细粉体。研发了“无旋立式 循环撞击流反应器”等多种基于应用LIS 的反应、结晶技术装备并已付诸应用。描述了这些装备的流动结构、 工作原理和工业应用情况。 关键词：撞击流 微观混合 压力波动 反应器 结晶器 中图分类号：TQ52 文献标识码：A Features of LIS intensifying processes and development and applications of the related technical devices Yuan Wu*, Yuxin Zhou, Jia Guo, Jun Yuan School of Chemical Engineering and Pharmacy, Wuhan Institute of Technology Key Laboratory for Green Chemical Processes of Education Ministry and Hubei Province Wuhan 430073, PR China Abstract Liquid-continuous impinging streams (LIS) has the excellent features of enhancing micromixing, strong pressure fluctuation and promoting process kinetics, which are extremely valuable for processes occurring on molecular scale . The authors investigated in depth these features ; and also studied the preparation of several “ultrafine” and nano materials experimentally by reaction-precipitation in LIS, and obtained products of smaller particles with narrower size distributions and controlled appearance. Several devices employing LIS for reaction and crystallization have been developed and applied, of which the flow configuration, working principles and industrial application status are described in this paper. Keywords : impinging streams, micromixing, pressure fluctuation, reactor, crystallizer 引 言 撞击流(impinging streams, 简记为IS)是较新颖的化学工程技术。其概念最初由Elperin[1]针对气 固相体系提出，目标是强化相间传递。由于其性质优越、具有应用的潜力，之后各国学者进行了广 [2] 泛的研究 ；撞