Cr含量对Fe_Cr_Ni镀层电化学腐蚀性能的影响.pdfVIP

37 5 2008 10 Vo.l 37 No. 5 Oct. 2008 SURFACE TECHNOLOGY 13 Cr FeCrNi , , , (, 450007) [ ] 以硫酸盐和氯化盐为主盐, 将 C r以微粒形式悬浮于镀液中, 电沉积 FeCrN i复合镀层, 用电化学方法研 了镀液 中 Cr粉含量对电沉积 FeCrN i复合镀层在 NaC l介质中的腐蚀行为的影响结果表明: 在镀层的浸泡试验中, 溶液中 C r粉含量为 100g /L 获得的镀层自腐蚀电位是最负的动电位扫描显示, 镀层都有钝化性能但对于溶液中 Cr粉含量为 100g /L 获得的镀层出 现明显的过钝化, 其耐蚀性能较差 [ ] FeC rN i; 镀层, 腐蚀行为, 电沉积 [ ] TQ 153. 2 [] A [] 1001- 3660( 200 ) 05- 0013- 02 Effect of t e Content of Cr in Electrolyte on Electroc em ical Corrosion Be avior ofE lectrodeposited FeCrN i Coating X I Yan j un, LI U Yong j un, WANG Zh ix in, L U J in b in, (M aterial and Chem ical Engineering School, Zhongyuan Un iversity ofT echnology, Zhengzhou 450007, Ch ina) [Abstract] The FeCrN i coating w as electrodeposited from chloridesulphate electrolyte. The effect of the con tent of Cr in electrolyte on the electrochem ical corrosion behavior of electrodeposited FeCrN i coating in NaCl solution w as investigated. The results show that the corrosion potential of the coating is negative w hen the content of Cr is 100g/ L during mi mersion test. In add ition, the coating show spassivation behavior. When the content of Cr is 100g/L in the e lectrolyte, the coating show s overpassivation phenom enon, and then the coating exhibits poor corrosion resistance. [Keywords] FeCrN i; Coating; Corrosion behavior; Electrodeposition 30g/L N iC l 6H O, 40g/L, ( ) g/L, 0 2 2 2 () 0. 1g/L, 25g/L, 5A /dm , 5 , Cr 50g /L100g/L150g /L, pH 3. 5, , ,