CV_AAS法快速测定皮革中痕量镉(西部皮革).pdfVIP

33 卷第8 期 西 部 皮 革 Vol.33 No.8 第 8 期 2011 年4 月 WESTLEATHER Apr.2011 CV-AAS 法快速测定皮革中痕量镉 1 2 2 1 1 1 蒋小良 ，邓小文 ，张海娟 ，叶林 ，李天宝 ，李达光 （1.江门出入境检验检疫局，广东江门529000 ；2.广州出入境检验检疫局，广东广州510000） 摘 要：研究了测定皮革中痕量镉冷原子化的反应体系，对载气流速、NaBH4 浓度、增敏剂加入量和介 质酸度的影响，以及基体和共存离子的干扰进行了研究。在试验选定的最佳条件下，用于皮革中痕量 镉的测定，回收率为96.2％～103.8％，方法检测限为0.015 μg ·L -1 ，相对标准偏差小于3.5%。 关键词：快速测定；冷蒸气发生；皮革；镉；增敏剂 中图分类号：TS 57 文献标识码：A 文章编号：1671-1602 （2011）08-0055-03 Rapid Determination of Trace Cadmium in Leather by Cold-Vapor Generation-Atomic Absorption Spectrometry 1 2 2 1 1 1 JIANG Xiao-liang , DENG Xiao-wen , ZHANG Hai-juan , YE Lin , LI Tian-bao , LI Da-guang (1.Jiangmen Entry-Exit Inspection and Quarantine Bureau, Jiangmen 529000, China; 2. Guangzhou Entry-Exit Inspection and Quarantine Bureau, Guangzhou 510000, China) Abstract: Trace cadmium in leather was determined by cold -vapor generation atomic absorption spectrometry. The influences of flow velocity of carrier gases, concentration of NaBH4 (sodium boron hydride), volume of sensitization reagents, acidity and interference of coexisting ion were tested. It can be used in the determination of trace amounts of cadmium in leather, the recoveries are in the range of 96.2% -103.8%, and the check limit is 0.015 μg ·L -1, with relative standard deviation(RSD) below 3.5%. Key words: rapid determination; cold-vapor generation; leather ；cadmium; sensitization reagent [5]