耐水性室温自交联核壳结构丙烯酸酯乳液的合成和表征.pdfVIP

全国中文核心期刊 耐水性室温自交联核壳结构 丙烯酸酯乳液的合成及表征 刘继承，胡剑青，王锋，涂伟萍 （华南理工大学化学与化工学院，广东 广州 510640） 摘要：采用核壳结构种子乳液聚合法，以双丙酮丙烯酰胺（DAAM）和己二酸二酰肼（ADH）为交联单体，合成了具有良好耐水性 的室温自交联核壳结构丙烯酸酯乳液；研究了交联单体的用量、交联温度、复合乳化剂用量及配比等对乳液性能的影响。FTIR 测试 证实了交联反应的发生；乳液的粒径图、DSC 曲线和TEM 表明，乳液具有2 个玻璃化转变温度，具有明显的核壳结构。 关键词：丙烯酸酯乳液；耐水性；核壳结构；室温自交联；双丙酮丙烯酰胺；己二酸二酰肼 中图分类号：TQ331.4 文献标识码：A 文章编号：1001-702X （2010）01-0070-05 Synthesis and characterization of water-resistance core-shell structure ambient self-cross-linking acrylic emulsion LIU Jicheng ，HU Jianqing ，WANG Feng，TU Weiping （College of Chemistry and Chemical Engineering ，South China University of Technology ，Guangzhou 510640 ，Guangdong，China） Abstract ：Taking diacetone acrylamide （DAAM）and hydrazide adipate （ADH）as the cross -linking monomers ，the core -shell structure ambient self-cross-linking acrylic emulsion with good water-resistance was synthesized by core-shell structure seed emul － sion polymerization method. The effects of the amount of cross -linking monomer ，different cross -linking temperatures and the amount and ratio of compound emulsifier on emulsion properties were discussed. FTIR test confirmed the occurrence of cross-link － ing reaction ；the emulsion particle size chart ，DSC curve and TEM test showed that the emulsion had two different glass transition temperatures and had a clear core-shell structure. Key words ：acrylic emulsion ；water-resistance ；core-shell structure ；ambient self-cross-linking ；diacetone acrylamide ；hydrazide adipate 的开发已成为研究的热点之一。 0 前 言 本研究以双丙酮丙烯酰胺（DAAM）为交联单体，以己二