钒铬还原渣富氧焙烧-碱浸提钒工艺研究.pdfVIP

·18· 蒋霖，等：钒铬还原渣富氧焙烧-碱浸提钒工艺研究 中国攀枝花 钒铬还原渣富氧焙烧-碱浸提钒工艺研究 蒋 霖，伍珍秀 (攀钢集团研究院有限公司 钒钛资源综合利用国家重点实验室 四川 攀枝花 617000) 摘 要：利用富氧焙烧-碱浸提钒工艺，分离回收钒铬还原渣中的钒、铬。探讨了焙烧与浸出条件对钒、铬浸出率 的影响。结果表明：在富氧气氛下，适当提高焙烧温度和延长焙烧时间有利于低价钒的氧化，从而提高钒的浸出 率；选用 NaOH 作为浸出介质，有利于钒的浸出，且铬的浸出很少；适当提高碱液浓度和延长浸出时间效果更佳； 浸出温度对钒、铬的浸出影响较小。钒铬还原渣在 880℃下富氧焙烧2h 后经 3mol/L NaOH 溶液在液固比 4:1 、温 度 70℃下浸出 1h，钒的浸出率达 92.36%，铬的浸出率小于 6% 。含钒碱浸液经酸性铵盐沉钒方式回收其中的钒， 铬渣可另作它用。 关键词：钒铬还原渣；富氧焙烧；碱浸 Technological Study on Vanadium Extraction from the Reduced Vanadium-Chromium Precipitate by Oxygen-enriched Calcination and Alkaline Leaching Jiamg Lin ,Wu Zhenxiu (Pangang Group Research Institute Co., Ltd., State Key Laboratory of Vanadium and Titanium Resources Comprehensive Utilization, Panzhihua 617000, Sichuan, China) Abstract: The separation and recovery of chromium and vanadium from the reduced vanadium-chromium precipitate were successfully implemented by oxygen-enriched calcination followed by alkaline leaching. The factors during calcination and leaching that affect the leaching rate of vanadium and chromium were investigated. The results indicated that it was beneficial for the oxidation of low valent vanadium to increase calcination temperature and time appropriately, so as to improve the leaching rate of V O . As the leaching medium, NaOH contributed to the leaching of V O , while the 2 5 2 5 leaching rate of Cr O was very low. Increasing NaOH concentration and time favored for leaching of 2 3 V O , while temperature had little effect on leach