钒渣钙化焙烧硫酸浸出液除磷实验研究.pdfVIP

·34· 唐红建：钒渣钙化焙烧硫酸浸出液除磷实验研究 中国攀枝花 钒渣钙化焙烧硫酸浸出液除磷实验研究 唐红建 （攀钢集团研究院有限公司，钒钛资源综合利用国家重点实验室 四川 攀枝花 617000） 摘 要：概述了钒渣钙化焙烧-硫酸浸出工艺的创新意义及控制环节，系统探索了除磷剂 X 加入量、酸浸液 pH 、 反应温度及反应时间对磷去除率和钒损失率的影响。结果表明：除磷剂 X 除磷实践可行，在除磷剂加入量为 10g、 酸浸液 pH=2.25 、反应温度为 60℃和反应时间为 25min 的较优条件下，钒渣钙化焙烧硫酸浸出液中的磷浓度从 0.13g/L 降低至0.04g/L，满足后续沉钒工艺要求；钒浓度从24.63g/L 小幅下降为 24.13g/L 。 关键词：钒渣；钙化焙烧；含钒酸浸液；除磷 Research on Removal of Phosphorus in Acid Leaching Solution Containing Vanadium Tang Hongjian （Pangang Group Research Institute Co.Ltd.,State Key Laboratory for Comprehensive Utilization of Vanadium and Titanium Resources,Panzhihua 617000,Sichuan,china） Abstract ：The innovative significance and control links of calcified technology of vanadium extraction from vanadium slag were summarized. The effects of reaction temperature, reaction time, amount of phosphate removing agent and solution pH value on phosphate removal rate and vanadium lose rate are systematically explored. Results showed that phosphate concentration was decreased from 0.13g/L to 0.04g/L under the optimum condition of reaction temperature of 60 ℃, reaction time of 25minutes, solution pH value of 2.25 and phosphate removing agent of 10g. after phosphate removing process, the concentration of phosphate met the precipitation process requirement and the vanadium concentration was decreased from 24.63g/L to 24.13g/L. Key words ：Vanadium Slag; calcium roasting; Acid Leaching Solution Containing Vanadium; phosphorus removal 0 引言 战。钠化焙烧-水浸工艺属于典型的劳动密集型工 [1] 业，低端产品产能过剩、产品纯度低、杂质种类众 钒渣钠化焙烧-水浸提钒 工艺综合回收率高， 多、产品同质化现象严重[4]，在一定意义上限制了 工艺成