温度对钙矾石生长特性的影响.pdfVIP

2011 32 3 DOI: 10. 3963/ j. cn.421783.T U. 2011. 03. 003 陈凤琴 ( , 430070) : 实验研究了合成温度对水泥水化产物钙矾石微观形貌和生长特性的影响利 XRD 和 SEM 等测试方 法对常温和 50 溶液反应法合成的钙矾石进行了定性分析, 利 T GDSCDTG 对常温溶液法合成的钙矾石进行了 热稳定性分析结果表明: 常温和50 溶液法均可以合成钙矾石, 其中常温溶液法合成的钙矾石晶体形貌表现为细 棒状, 晶体长约2 3 m, 宽约0. 5 m; 50 溶液法合成的钙矾石晶体形貌为细针状, 晶体长约0. 5 1. 0 m, 宽约 0. 1 m提高溶液反应温度,钙矾石微观形貌有所变化, 晶体形貌变得细小, 温度的升高促进了钙矾石晶体晶核的形 成以及晶体的生长 : 温度; 钙矾石; 微观形貌 Effect of Temperature on the Growth Characteristics of Ettringite CH EN Fengqi n ( School of Materials Science and Engineering, Wuhan University of Technology, Wuhan 430070, China) Abstract: T he effect of synthesis temperature on the morphology, grow th characteristics and thermal stability of ett ringite w as studied by XRD, SEM and TGDSCDTG t echnique. The results indicated that the ettringite synthesized by solution react ion method at the room temperature w ere thin rodlike with the length of around 2 3 m and the thickness of 0.5 m, w hereas those synthesized at 50 w ere thin needleslike w ith the length of around 0.5 1. 0m long and t he t hickness of 0. 1 m. T em perat ure affects the microstructure of ettringit e, leading to the crystal of ett ringite becom ing more thick. The temperature promoted the formation of crystal nucleat ion and crystal grow th of ett ringite. Key words: temperature; ettringite; morphology (AFt , 3CaO Al2 O3 3CaSO4 32H2 O) , 7%, 25%, , , , , , , [ 1] , , [ 2] , 7 , [ 3] , , X Denise A Silva X : ( 973 ) (2009CB23200) . : ( 1985) , .Email:chenzhang0910@ 163.com