1_4_甲苯基_2_4_氨基苯基_乙烯的合成.pdfVIP

218 精 细 化 工 Vol. 2 1, No . 8 20 04 8 FINE CHEMICALS Aug. 2 0 0 4 1-( 4-)-2-(4- ) 李祥高, 王文保, 李 蓉, 侯 薇 ( , 300072) : 1-(4- )-2-( 4- ) 4- Wittig , 4-1-(4- )-2-( 4-) , : 95~ 100 , n( ) / n( ) = 5, 027 mol/ L, 7 h, 78 % : ; ; :TB34 :A : 1003- 5214(2004) 08- 05 3- 04 Synthesis of 1-(4-Methylphenyl)-2- (4-aminophenyl) ethylene LI Xiang-gao, WANG Wen-bao, LI Rong,HOU Wei (Department of Fine Chemicals, School of Chemical Engineering and Technology, Tianj in University, Tianjin 300072, China) Abstra t: 1-( 4-Methylphenyl )-2-( 4-aminophenyl) ethylene is one of the important intermediates for preparing hole transport materials of styryl triarylamines. In this paper, the objective compound was synthesized through the reaction of 4-nitrobenzaldehydewith the Wittig reagent prepared from 4-methylbenzyl chloride and triphenylphosphine and reduction of the resulting 1-( 4-methylphenyl)-2-( 4-nitrophenyl) ethylene. The influencing factors of reduction were studied and the optimum reaction conditions were obtained.Thus, the reaction was carried out at 95~ 100 for 7 h with n( Fe) / n( nitro-compound) = 5 and the nitro-compound of 027 mol/ L to get the highest yield of 78 % . Key words:hole transpart material; styryl triarylamine; reduction Foundation item: Supported by the national high technology research and development program of China ( 2002AA325050) , , ( OLED) [ 1] [2] ( [ 3] ) , , Ullmann , , Wittig , , Ullmann , , ,