PAN基高模碳纤维阳极氧化的表面处理.pdfVIP

化 工 进 展 558 CHEMICAL INDUSTRY AND ENGINEERING PROGRESS 2007 年第26 卷第4 期 PAN 基高模碳纤维阳极氧化的表面处理 1, 2 1 1 侯永平 王浩静 李东风 1 中国科学院炭材料重点实验室 中国科学院山西煤炭化学研究所 山西 太原 030001 2 中国科学院研究生院 北京 100039 摘 要 采用阳极氧化法对PAN基高模碳纤维进行连续表面处理 重点研究了氧化电流密度对碳纤维宏观力学性 能 表面形貌 表面酸性官能团以及碳纤维增强树脂基复合材料 CFRP 层间剪切强度 ILSS 的影响 结果表 明 电流密度对纤维力学性能 表面形貌影响不大 氧化后纤维表面总的酸性官能团显著提高 最大增幅达13倍 左右 适当的处理条件可使CFRP的ILSS从28.4 MPa提高到80 MPa 以上 关键词 PAN基高模碳纤维 阳极氧化 层间剪切强度 中图分类号 TQ 342.743 文献标识码 A 文章编号 1000 –6613 2007 04 –0558 –05 Anodic oxidation of PAN-based high-modulus carbon fibers HOU Yongp ing1, 2 WANG Haoj ing1 LI Dongfeng 1 1 ( Key Laboratory of Carbon Materials, Institute of Coal Chemistry, Chinese Academy of Sciences, Taiyuan 030001, Shanxi, China; 2Graduate School of Chinese Academy of Sciences, Beijing 100039, China) Abstract: PAN-based high-modulus carbon fibers were continuously treated by anodic oxidation. The influence of anodic oxidation on macroscopic mechanical properties, surface morphology, surface acidic functional groups, interlaminar shear strength of the carbon fiber reinforced plastic (CFRP) was studied. In conclusion, macroscopic mechanical properties and surface morphology of CF were not influenced by anodic current density. After oxidation, the maximum amount of total surface acidic functional groups increased to 13 times that of untreated CF. Appropriate oxidative conditions could increase interlaminar shear strength from 28.4MPa to 80MPa. Key words: PAN HM carbon fiber anodic oxidation interlaminar shear strength (ILSS) 碳纤维(CF)具有高比强度 高比模量 耐