低温燃料电池非铂催化剂研究进展.pdfVIP

Chinese 催化学报2013年934卷96期1wvgw．chxb．cn JournalofCatalysis34 2013 1051-1065 availabIeatwww．sn cie cedirect．com 。：j：，ScienceDireCt urnaIhome sevie oc h r．com／I c jo ELSEVIER Review ’一 ■ l _ _ - ’ 1‘ ■● ● ’ ln with lnloW ProRressnon-platinumcatalystsaDDllCatlonS fuelcells temperature c抖 ZHANG Shuihua YUWeifei 8，b，一，TANG Jie 8，-，LIAOLongyucp 610500,Sichuan,Chino 61050D，Sichuan,China 6SchoolofMaterialsandEngineering,SouthwestPetroleumUniversity,Chengdu ‘lnstRuteofChemicalMaterials,ChinaAcademyofEngineeringPhysics,Mianyanfl62190谚Sichuan,China ARTl CLE l NF0 ABSTRACT Article have attracted attentionwith totheir history： Non—platinumcatalystsrecently significant regard potential Received1December2012 in fuel the low cells．Thisreviewsummarizes inthe applicationstemperature progressesdevelop- 25March2013 mentofthese to anodeandcathode basedon Accepted catalystsdate．including catalysts．Anodecatalysts Published20 2013 metal oxides June carbides，Pd are ontheir alloys，andperovskite described，focusingcatalyticactivity． The cathode includetransitionmetaI ni． non—platinumcatalysts macrocycliccompounds．metal metal arediscussedin active trides．and sites， oxides．Particularly,variousaspects detail，including Keywords： the for com— interactions，and transitionmetal ruelcell metal-support preparationparameters macrocyclic the reviewed findcommer- areconsidered candidates曲ae pounds．Allcompounds promising may Non-platinumcatalyst cial as anodeandcathode for cells． fuel Methanoloxidation applicationsnon·platinum catalysts @2013．DalianInstituteofChemical ofSciences． reductionreaction Physics．ChineseAcademy Oxygen PublishedElsevierB．V．AIl reserved． by fights 1。In订oduction tlleelectrodestructuresandits arecata． optimize f41．Pt alloys for most Pt the usedDMFCsbecauseexhibits 1ysts commonly Low ruelcells below100。C。suchas remarkableforboth reduction temperatureoperating activity oxygen fuel knownas andmethanoloxidaUon hydrogen／oxygencells also protonexcha