MFI型分子筛膜的制备及表征.pdfVIP

34 10 Vo.l 34 No. 10 2006 10 CHEM ICAL ENGINEER ING( CH INA ) Oct. 2006 MFI 袁文辉, 罗仡科, 胡小芳 ( , 510640) : , A l O MFI, XRD, SEM 2 3 , A l O MFI / 2 3 298 K 473 K 77 70, , 2, , MF I 5% 50% 95% / , , ; , : ; ; : TQ 028. 8 : A : 2006) Preparation and gas permeation properties of MFItype zeolitem embrane YUAN W enhui, LUO Yi e, HU X iaofang ( R s arch Institut of Ch m ical Engin ring, South Ch inaUn iv rsity of T chnology, Guangzhou 510640, Guangdong Provinc , China) Abstract:MF Ityp z olit m mbran s w r pr par d on A l O substrat by s condary grow th synth sis w ithout 2 3 t mp lat . XRD, SEM and gas p rm ation xp rmi nts w r app li d to charact r iz th z olit m mbran . Id al s paration factors of nbutan /ibutan on MFItyp z olit m mbran by s condary grow th synth sis ar up to 77 and 70 r sp ctiv ly at 298 K and 473 K. Th data of gas s paration indicat d that th s paration w as dom inat d by mol cu lar si ving m chan ism on two z olit m mbran s fr of d f cts. Th s paration factors of th EtOH /H O 2 solutions w ith th EtOH mass fraction of 5%, 50% and 95% on MF I z olit m mbran s w r obtain d by p rvaporation at d iff r nt t mp ratur s. Th r sults show that w h n incr asing t mp ratur th p rm anc s of EtOH /H O incr as