PCABS的界面张力问题.pdfVIP

Full Paper Effect of ABS Rubber Content on the Localization of MWCNTs in PC/ABS Blends and Electrical Resistivity of the Composites Yao Sun, Zhao-Xia Guo,* Jian Yu* Three types of acrylonitrile-butadiene-styrene rubbers with different rubber contents were used in the preparation of PC/ABS/MWCNT composites. It was found that localization of MWCNTs changes from PC to ABS phase when rubber content of ABS varies from 5 to 60%. This is discussed by a combination of thermodynamics and kinetics. Melting sequence and high viscosity of ABS are used to explain the localiz- ation of MWCNTs in the high viscosity ABS phase. The relationship between the localization of MWCNTs and the electrical resistivity of the com- posite is also investigated. Introduction predicted thermodynamically by the wetting coefficient that can be calculated using Sumita’s model.[25] When Conductive filler-filled immiscible polymer blends are of thermodynamic equilibrium is not reached or could never interest over the last two decades,[1–23] because the be reached, kinetic factors are decisive for localization of the electrical percolation threshold could be significantly conductive filler. For example, Gubbels et al.[2] found that lowered compared to those of the corresponding single the electrical resistivity of CB-filled polyethylene (PE)/ polymer-based composites. The conductive filler is usually polystyrene (PS) blends changed as a function of mixing selectively localized in one polymer phase or at the interface time, corresponding to different localizations of CB, with of a co-continuous structure. The lowest percolation the lowest electrical resistivity when CB is localized at the threshold was found when the con