分析化学测试题.docVIP

ⅠSingle choice ( 2 points per question, 30%) (一) 1. When 0.20mol?L-1 NaOH standard solution was used to titrate the mixtures of 0.10 mol?L-1H2SO4 and 0.10mol?L-1H3PO4, ________end points could be observed on the titration curves. （ ） A. 1 B. 2 C. 3 D. 4 2. Which one of the following is a pair of conjugate acid and base? ( ) A. H2CO3—CO32- B. HPO42-—PO43- C. H3PO4—HPO42- D. NH3-NH3.H2O 3. The solubility of Ag2S in pure water is________(KSPAg2S=2.0×10-48)( ) A. B. C. D. 4. Which of the following could be used as the primary standard?( ) A. KMnO4 B.（NH4）2CO3 C. HCl D. K2Cr2O7 5. The equilibrium constant for the reaction of MnO4- and Fe2+ is ______ (E0 (MnO4-/Mn2+)= 1.51 V; E0 (Fe3+/Fe2+)=0.77V ) ( ) A. 320 B 3.4(1012 C 5.2 (1062 D 4.8(1063 6. ( of a absorbing complex is always dependent upon the______( C ) A. the stability of the complex B. the thickness of the container C. the wavelength of the electromagnetic radiation D. the concentration of the comples 7. A solution containing commercial cyt c is buffered to pH 7.40 using 85 mmol/L phosphate buffer. If the solution is diluted with water by a factor of three, what is the resulting pH of the solution? ( D ) A. 2.47 B. 5.15 C. pH 14 D. nothing happens - pH remains same 8. The %T of a certain solution at a certain wavelength in a 1.0 cm cell is 50%. The absorbance of this same solution in a 2.0 cm cell is: ( ) a) unknown. We cant calculate it with the information given. b) 0.15 c) 0.30 d) 0.60 9. What is the ratio of acid to salt in a solution that is pH 7.20 and contains H3PO4 and Na3PO4 (pKa1~pKa3 of H3PO4 are 2.12、7.20、12.4 respectively) ( ) a) 1:2 b) 2:3 c) 1:1 d) 2:1 10. A series of solutions containing NaOH, Na2CO3, and NaHCO3 alone or in compatible combination, was t