分析化学张曼曼.pptVIP

Study on adsorption of wastewater treatment by zeolites Reporter:Zhang Manman Major: Analytical Chemistry Tutor: Han Runping Content Background China is in short of water resource and the pollution of water resource is great. So it is important to find an effective and inexpensive material to treat the wastewater. Zeolite is a perfect adsorbent to treat wastewater. Background Zeolite molecular sieves are a well known aluminosilicate family of inorganic adsorbents. Its molecular formula is (Na ,K)x(Mg ,Ca ,Sr ,Ba)y {Al ( x + 2y) Si[n - ( x + 2 y) ]O2 n} ·m H2O Natural and synthetic zeolites are microporous high surface crystalline and hydrated aluminosilicates of alkali and alkaline earth cations with an infinite, open and rigid three dimensional structure. The three dimensional framework consists of (AlO4)5 – and (SiO4)4 – tetrahedral units linked through shared oxygens. Thanks to the unique chemical structure, they exhibit excellent ion exchange, adsorption and catalytic properties. Due to these characteristics, these inorganic materials have been receiving a lot of attention for possible applications in wastewater treatment. Current research Chengshi et.al utilized modified analcime for defluorination from drinking water, the modified method is after hyperthermia activated, then use aluminum sulfate solution to treat . Li zengxin et.al treat copper(Ⅱ) in wastewater by natural zeolite-chitosan compound adsorbent. The research of our laboratory : Adsorption of Malachite Green(MG) from the Aqueous Solutions by natura zeolite and Microwave-regeneration for Spent Zeolite . The result shows that the value of pH 4-5 is favorable for removal of the MG; the greater adsorptive quantity was observed with the higher temperature or the larger initial concentration of MG.The maximum capacity of adsorption equilibrium is 22.3 mg·g-1.The spent zeolite, which is used to removal of malachite green （MG） from aqueous solution, is regenerated by microwave and the regenerati