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. Angewandte N. V. Izarova et al. Reviews DOI: 10.1002/anie.201202750 Polyoxometalates Noble Metals in Polyoxometalates Natalya V. Izarova,* Michael T. Pope,* and Ulrich Kortz* Keywords: In memory of Ann Pope addenda atoms · cluster compounds · heteropolyanions · noble metals · polyoxometalates Angewandte Chemie 2012 Wiley-VCH Verlag GmbH Co. KGaA, Weinheim Angew. Chem. Int. Ed. 2012, 51, 2 – 21 These are not the final page numbers! Angewandte Polyoxometalates Chemie Polyoxometalates containing noble metal ions, such as ruthenium, From the Contents osmium, rhodium, palladium, platinum, silver and gold, are a struc- 1. Introduction 3 turally diverse class of compounds. They include both classical heteropolyanions (vanadates, molybdates, tungstates) in which noble 2. Polyoxovanadates, -molybdates, metals are present as heteroatoms, as well as the recently discovered and -tungstates 3 class of polyoxometalates with noble metal “addenda” atoms. The focus of this Review is on complexes that should, in principle, exist as 3. Polyoxo