toc法赤潮监用材料及其集成系统研制.pdfVIP

摘 要 浮游生物在某些情况下突然性地暴发性增殖产生的赤潮，会给海洋环境及业绩海洋生 态带来极为严重的影响。本文旨在研制出一种新型的TOC 法赤潮监测材料及其集成系统， 使之能够更好的对赤潮的发生过程进行预警与监测。主要研究内容及成果包括以下几个方 面： 首先根据以往TOC 仪器的设计方法、海水水质的特殊性以及实时监测的特殊要求，设 计实现赤潮监测预警的流程图。根据流程图选择，选择部件材料、研制各种部件，最终组 装成一台试验用TOC 法赤潮监测系统。 其后，对系统进行不同水质情况下准确性、重复性、检出率等技术指标进行验证，以 确定系统反应器辅热温度及响应时间，利用一系列实际水样对系统的TOC 测定效果表明， 该系统的线性相关系数大于0.999 ，回收率在95%至105%之间，RSD 均小于等于1%，系 统的氧化器辅加温度确定为 60℃，响应时间=8min 。测试结果表明，此系统的各项性能均 达到了有关技术要求的规定，证用所选用的材料及系统部件具有较好的实用性及准确性。 最后，通过人工培养海洋浮游生物的生长过程，利用叶绿素A 含量、生物量、浊度等 传统测定方法与本系统的TOC 测定值进行对比，结果表明本系统的TOC 变化趋势与传统 方法测定的变化趋势基本一致，由此验证了用TOC 的测定值来表示浮游生物生长过程的可 行性，进一步证明了选用的材料、系统部件合理性及TOC 法赤潮监测系统可行性。 关键词：TOC 赤潮 监测材料 监测系统 环境监测 分析仪器 ABSTRACT In some cases, phytoplankton may have sudden propagation, and cause red tide, which can bring adverse affecting to the marine environment and marine ecosystems. This paper is mainly about researching a type of new mo nitoring system of TOC to monitor red tide for the better. The chief contents and results are as follows: Initially, according to the design method, particularity of the sea water quality and special requirements of real-time monitoring of the earlier TOC instruments, we design the flow chart of early warning of the red tide. Based on the flow chart, we choose material and develop all kinds of components, at last, we assemble a instrument, with monitoring system of the red tide. We verify the accuracy, repeatability and detection rates of the systems in different water qualities, get the reactor auxiliary heat temperature and response time, identify the actual effects by monitoring TOC in the actual water samples. We know that the linear correlation coefficient is higher than 0.999, the average recovery rate is from 95% to 105%, RSD is better than 1%, and auxiliary temperature of the oxidation is intended to