《BYD磷酸铁锂电池性能测试.》.ppt

BYD COMPANY LIMITED * LiFePO4 performance * Outline What is LiFePO4? Discharge curve GSM discharge High temperature Storage Low temperature discharge Cycle life Overcharge Fire exposure * What is LiFePO4? LiFePO4 is a new kind of positive material. LiFePO4 also has the function that release or receive Li-ion like LiCoO2. LiFePO4 Olivine structure FePO4 Olivine structure LiFePO4 Charge Discharge * Discharge curve LiFePO4 has the same discharge curve as LiCoO2. LiFePO4 has the lower MPV (Mid-point voltage) than LiCoO2. MPV of LiFePO4 is 3.1~3.2V, MPV of LiCoO2 is 3.6~3.7V. * GSM discharge Following shows GSM discharge curve (cut off voltage is 2.8V). GSM1/0.2C GSM2/0.2C 1# 90.3% 86.0% 2# 88.9% 84.7% * High temperature Storage Following show storage results of LiFePO4 and LiCoO2 system . Storage condition Capacity keeping ratio (capacity after storage / capacity before storage) Capacity recovering ratio (capacity after recharge / capacity before storage) 60℃, 7days 85.2% 92.8% 85℃, 48hours 75.1% 80.2% Storage condition Capacity keeping ratio (capacity after storage / capacity before storage) Capacity recovering ratio (capacity after recharge / capacity before storage) 60℃, 7days 83.1% 89.2% 85℃, 48hours 72.5% 79.3% LiCoO2 LiFePO4 * Low temperature discharge Following shows discharge of different temperature. Temp. 60℃/25℃ 45℃/25℃ 0℃/25℃ -10℃/25℃ -20℃/25℃ ratio(%) 93.4 98.2 72.6 64.2 45.4 * Cycle life LiFePO4 structure keeps stable before and after discharge, so it has good cycle life. Basing on experience of other projects, LiFePO4 cycle life can be more than 1000. Olivine structure FePO4 Olivine structure LiFePO4 Charge Discharge * Overcharge LiFePO4 has good safety performance. Following show 1C/12V overcharge result. Condition Cell No. Max temp. Phenomena Result 1C/12V 260# 117.10℃ Swelling, vent open lightly, no fire, no explosion. Pass 253# 120.05℃ Pass 271# 120.64℃ Pass * Overcharge Following show 1C/12V overcharge curve and cell photos. Before test After test *