几种荧光分子探针的设计、合成和离子识别性质研究.pdf

Abstract Abstract Becauseofthe offast and advantages sensitivity response，high selectivity, detection low limit，easy molecularale operation,etc，fluorescentprobeswidely inthedetectionofvarious metal applied transitionand metalions．Inthis heavy condensation andDiels．Alder seriesofnew thesis，through reactions，a fluorescent were and fortheir in probessynthesized thedetectionof investigated applications transitionmetal ions(Zn2+，Fe3+)andheavy metal(Cu2+)，whichpossess as atomas 1，8。naphyridine／aromatic compoundfluorophore，nitrogencomplexation atom．Some as resultsarefollows： interesting 1．A fluorescentforzincion 1，8。naphthyridine-based not exhibitsa probe only large increaseofemission in detectszincionsinthe intensityethanol，but selectively of metal showthatthe presencecompetingions；moreover,cell aimed experiment calldetect product intracellularZn十． 2．A fluorescentCwas and asan“off-on’’Zn2+and probe designed