超级电容技术前沿进展.pdfVIP

Recent Development of Recent Development of Supercapacitor Technologies Supercapacitor Technologies 超级电容技术前沿进展 超级电容技术前沿进展 高立军 南昌大学 Background Background B.Sc. Chemistry, Peking University, 1987 北 京大学化学系 Ph.D in Electrochemistry, University of Ottawa, Canada, 1994 (with Prof. B.E. Conway, pioneer of supercapacitor) 16 years experience in Canada and USA Professor of Nan Chang University, 2005 Research in electrochemistry, high energy, hybrid supercapacitors Why Supercapacitor Why Supercapacitor Power energy device Superior than batteries: – High power density ( 1 kW/kg, or 100 F/g) – High cycle life (0.1 - 0.5 million cycles, or 10 – 20 years use) o o – Wide temperature range (-40 C – 60 C), – Safe, maintenance free Market size: 2.4 billion USD by 2009 worldwide Major applications: – Electronics (car audio, electric meter, memory backup) – Automobiles (electric and hybrid vehicles) – Utilities (UPS) – Power equipment (harbor lifting equipment) – Military, aerospace Principle Principle Technology Characteristics Technology Characteristics 2 电化学电容(EDLC) ~ 20 uF/cm , 2 – 活性炭2000m /g, Cdl = 400 F/g 电极材料：活性碳(AC)，金属氧化物(RuO2,NiO2, PbO2)， 纳米炭管 电解质：有机溶液（PC, ACN), 水溶液（H2SO4，KOH） 2 2 能量E = 0.5 CV ，功率Pmax= V / 4Rs – commercial products 2-5 Wh/kg, 1-3 kW/kg, 100K cycles Asymmetric organic EDLC – 电压3V – 能量密度增加10% - 20% – 长寿命 Li-ion SC – 一半锂电正极（Li4Ti5O12, LiMn2O4 ），一半活性碳 – 15-20Wh/kg 提高比能量 Compare with Batteries Compare with Batteries Subject Technology Roadmap Subject Technology Roadmap 1950s-1960s GE