Chapter7Electrochemistry解说.ppt

Chapter 7 Electrochemistry（电化学）;New Words;New Words;7.1 Some Basic Concepts;1.Oxidation Number and Valence;Rules for Assigning an Oxidation Number (O.N.);Highest and lowest oxidation numbers of reactive main-group elements.;2.Redox Reaction;Oxidation-reduction or redox reactions are electron transfer reactions;2.Redox Reaction;3.Electrochemical Cell; electrical chemical energy energy ;3.Electrochemical Cell;4.Balancing Redox Reaction;Sample Problem;4.Balancing Redox Reaction;4.Balancing Redox Reaction;How to balance a redox reaction?;Balance the following equations, point out oxidizing and reducing agent;General Principle of half-reaction method: 1) In general, we begin with a “skeleton” ionic reaction, which shows only the species that are oxidized and reduced. 2) If the oxidized form of a species is on the left side of the skeleton reaction, the reduced form of that species is on the right, and vice versa. 3) Unless H2O, H+, and OH－ are being oxidized or reduced, they do not appear in the skeleton reaction.;5.How to compare the strength of oxidizing agent and reducing agent;5.How to compare the strength of oxidizing agent and reducing agent;6.Conjugate redox pairs ;6.Conjugate redox pairs ;6.Conjugate redox pairs ;7.2 Electrochemical Cell;I. Electrochemical Cell;1. Definition of Electrochemical Cell;2. Component of Electrochemical cell;2. Component of Electrochemical cell;An electrochemical cell based on the zinc-copper reaction.;2. Component of Electrochemical cell;2. Component of galvanic cell;2. Component of Electrochemical cell;2. Component of Electrochemical Cell;2. Component of Electrochemical Cell;2. Component of Electrochemical Cell;2. Component of Electrochemical Cell;3. Types and Notation of Electrode;（3）Redox electrode: Fe3+/Fe2+ ;4. Notation of Electrochemical Cell;4. Notation of Electrochemical Cell;II.