气体吸附理论及应用概论.ppt

多孔物质气体吸附 理论及应用概论 ;内容简介;颗粒特性分析测定仪器;;;QUANTACHROME;Founded 1968 by Dr. S. Lowell, Professor of Physical Chemistry, Long Island University, New York;Quantachrome’s Headquarters, Boynton Beach, Florida, USA;Quantachrome People;Quantachrome People;Quantachrome People;Quantachrome People;Quantachrome People;Quantachrome Firsts;Development of the first “commercially viable” gas-expansion pycnometers!;Development of the Monosorb?, the first single-point, dynamic-flow BET instrument with direct surface area readout!;Development of the patented continuous-scanning mercury porosimeters utilized in the Quantachrome PoreMaster? pore size analyzers!;Development of the Autosorb?-6, the first multi-station surface area and pore size analyzer with the ability to conduct independent and simultaneous measurements!;NOVA e系列全自动比表面及孔隙度分析仪;QUADRASORB SI;Autosorb-1MP 微孔型;Rifflers;多孔材料的物理吸附理论分析;;;什么是表面积? Surface Area – what is it?;为什么表面积如此重要?Surface Area – Importance?;孔的类型;孔形的分类;孔径的分类 (IUPAC Standard);表面积测定方法Suitable methods of determination;孔隙度测定方法---- 气体吸附法;孔隙度测定方法---- 压汞法;孔隙度测定方法---- 透射电镜;孔隙度测定方法---- 扫描电镜;孔隙度测定方法---- 小角X-射线扫描法;孔隙度测定方法---- 小角中子散射法(SAN); 吸 附 原 理 ;固体材料对气体的吸附现象;物理吸附和化学吸附的比较;气体吸附过程静态描述;气体吸附;气体吸附;气体吸附过程;吸附等温线;Very Low pressure behavior (micropore filling);Low pressure behavior (monolayer);Medium pressure behavior (multilayer);High pressure behavior (capillary condensation);Schematic illustration of the sorption, pore condensation and hysteresis behavior of a fluid in a single cylindrical mesopore;具有微孔的氮吸附等温线;由国际纯粹与应用化学联合会（IUPAC）提出的物理吸附等温线分类 ;I型等温线的特点;II型和III等温线的特点;IV型等温线的特点;V和VI型等温线的特点;迟滞回线类型;迟滞回线类型按照IUPAC 13.2节中的约定，划分出了4种特征类型;迟滞回线类型按照IUPAC 13.2节中的约定，划分出了4种特征类型;迟滞回线类型按照IUPAC 13.2节中的约定，划分出了4种特征类型;迟滞回线类型按照IUPAC 13.2节中的约定，划分出了4种特征类型;迟滞环与孔形的关系;气体吸附;气体吸附分析仪;测量方法;流动法 Flow;动态流动法Dynamic Flow;(经典的)真空-体积测定法(Classical) Vacuum-Volumetric;测量方法;真空法-气体体积测量关键;样品准备---- 必须让吸附质”看到”表面Sample preparation;表面脱气Outgassing of Surface;表面脱气Outgassing of Surface;真空脱气还是流动脱气?Vacuum or