電池-4.pptVIP

Rsei: SEI film resistance Rct: charge transfer resistance From two resistances Rsei and Rct for graphite electrode, the change of negative electrode/electrolyte interface and the formation mechanism of SEI film were analyzed. The effect of the VC addition into the electrolyte solution was investigated, and it has been clarified that the VC helps to form the high quality SEI film at the early period of first cycle charge. On the other hand, the Rsei took a large value by the addition of ES, suggesting the formation of thick SEI film on the graphite electrode. And the irreversible capacity was 3