DETERMINATION OF SILANOL NUMBER ON SILICAGEL PARTICLES BY硅silicagel粒子数测定.pptVIP

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DETERMINATION OF SILANOL NUMBER ON SILICAGEL PARTICLES BY硅silicagel粒子数测定.ppt

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Quantitative determination of surface area of silica gel particles by near infrared spectroscopy and chemometrics ALFRED A. CHRISTY Department of Mathematics and Sciences, Agder University College, Kristiansand, Norway Points to discuss 1. Silica gel Silica gel and its characteristics Silica gel and its importance Silanol number and surface area of the silicagel particles 2. Determination of surface area 3. Experimental 4. Results and discussion 5. Conclusion Silica gel and its characteristics Silicagel is prepared by the reaction of sodium silicate with hydrochloric acid Dry silica has a surface area of 200-800 m2/g Has a pore volume 0.7 cm3/g and average pore diameter of 80-150 ? The surface of the silica gel particles contain silanol groups (Si-OH) and siloxane groups (Si-O-Si) Some silanol groups lie buried in the bulk On heating above 200o C causes loss of OH groups OH groups are completely annihilated at 1200o C Silica gel and its characteristics Silica gel and its importance The silanol groups can form strong hydrogen bonds with water molecules The presence of silanol groups make silica an important material in separation science and in the field of catalysis The silanol groups can be chemically modified-different stationary phases for chromatographical applications Concentration of the functional groups on the Surface is a measure of the effectivity of a chromatographic column One of the parameters that are needed for the determination of this stationary phase effectivity is the surface area of the silica gel particles. Silanol number and surface area of the silicagel particles The properties of silicagel is connected to the Number of silanol groups per nm2 area on the surface (aOH) The methods used in the determination of silanol number 1. Theoretical calculation 2. Chemical methods 3. Physical methods All these methods conclude that the number of silanol groups on the silicagel surface is a constant with 4.55 OH/nm2 Water molecules are adsorbed o