一体式陶瓷膜乳化装置制备WO型乳状液的研究.pdfVIP

一体式陶瓷膜乳化装置制备W/O 型乳状液的研究 * 景文珩，吴俊，邢卫红，徐南平 ， 时钧 （南京工业大学膜科学技术研究所，江苏省材料化学工程重点实验室，江苏南京210009 ） . 摘要 本文研究了采用一体式的陶瓷膜乳化装置制备单分散的 W/O 型乳状液的方法。含2%SPAN80 的 -4mol·L-1 阳离子表面活性剂，0.16μm 的亲 煤油溶液被用作连续相，通过向分散相（水相）中添加 1×10 水性陶瓷膜可直接用于单分散W/O 型乳液的制备，具有较高的膜通量。搅拌速度对过程的影响也被考 察，在 0.1MPa、490rpm 的条件下，制备的乳液为单分散的，粒径在 1~2μm 之间，此时的膜通量为 -2 -1 5 -3 140.6L·m ·h ，能量密度为 5.63×10 J·m ，为简单搅拌过程在 3000rpm 条件下制备乳液的能耗的 0.16 倍。 关键词 陶瓷膜 膜乳化 单分散 乳状液 中图分类号 TQ027.3 TQ051.7 文献标识码 A W/O emulsions prepared by integrated ceramic membrane emulsification apparatus JING Wenheng, WU Jun, XING Weihong, XU Nanping and SHI Jun (Membrane Science Technology Research Center, Key Laboratory of Material-oriented Chemical Engineering of Jiangsu Province, Nanjing University of Technology, Nanjing 210009, China) Abstract Method for preparation of monodispersed W/O emulsions by integrated ceramic membrane apparatus was investigated. A hydrophilic ZrO2 ceramic membrane with a nominal pore size of 0.16μm was used as emulsification medium in this paper. Kerosene containing 2% SPAN80 was used as the continuous phase, water was the dispersed phase. By adding 1×10- 4 -1 mol·L cation surfactant (CTAB) into the dispersed phase, the hydrophilic ceramic membrane can be directly used as emulsification medium in the preparation of monodispersed W/O emulsions. Using the method, the flow resistance of liquid in membrane pore could be decreased and the flux of dispersion could be effectively increased. The influences of stirring speed on the process were investigated by experiments, monodispe