旋转填料床微观混合性能的CFD模拟.pdfVIP

旋转填料床微观混合性能的CFD 模拟 1 1 2 1 杨文婧 ，王运东 ，陈建峰 ，费维扬 1 （清华大学化学工程国家重点实验室，北京，100084 2北京化工大学教育部超重力工程研究中心，北京，10002） 摘要：旋转填料床又称为超重机，通过旋转产生的离心力来实现超重力环境，能有效的强化微混合及传质 过程，在快速反应过程上有广泛的应用，如制备纳米粉体材料。旋转填料床内的湍流反应涉及在填料中流 体流动与混合反应过程，针对两股无预混反应物料的湍流混合及反应，通过商用软件Fluent 的计算平台 ， 采用涡耗散模型（eddy-dissipation ）模拟了碘酸盐-碘化物体系的平行竞争反应。涡耗散模型认为反应速率 由湍流控制，避开了代价高昂的Arrhenius 化学动力学计算。计算过程收敛良好，流场与各组分浓度分布合 理，模拟还考察了转速及初始浓度对离集因子因子的影响，模拟结果与相关文献的实验数据吻合良好。 关键词：旋转填料床，微混合，模拟，快速反应，涡耗散模型 Computational Fluid Dynamic(CFD) Simulation of micromixing in a rotating packed bed YANG Wenjing 1, WANG Yundong 1*, CHEN Jianfeng 2 and FEI Weiyang 1 1 ( TheState Key Laboratory of Chemical Engineering, Department of Chemical Engineering, Tsinghua University, Beijing 100084, China 2Research Center of the Ministry of Education for High Gravity Engineering and Technology, College of Chemical Engineering, Beijing University of Chemical Technology, Beijing 100029, China) Abstract: Rotating packed bed (RPB), known as HIGEE, an acronym for high gravity has been widely used in absorption, desorption, distillation, oxidation, crystallization, precipitation, polymerization, production of nanoparticles. RPB utilizes centrifugal acceleration to intensify the mixing and mass-transfer processes. The turbulence reactions in RPB are include flows in the packings and mixing and reactions. Based on the computational platform, Fluent software, the turbulence reactions with two non-premixed solutions were simulated. The eddy-dissipation model was used to calculate the parallel competing reaction system, iodide-iodate system. In the eddy-dissipation model the overall rate of reaction is controlled by turbulent