材料化学全英文课件课.pptVIP

材料科学基础Fundamental of Materials Science 3.7 Intermetallic Compounds (Intermetallic Phases) 3.7.1 Feature 1. The structure of AmBn differs from those of either A or B 2. Its composition is variable to more or less extension 3. Mixed bonding 4. Intermediate properties 3.7.2 Formation A→←B The property of AmBn is between that of A and B. 3.7.3 Factor governing the structure of “compounds”. 1) Electrochemical factor (X) 2) Electron concentration (e/a) 3) Size factor Metal , Nonmetal , Metalloid 3.8 Normal Valence Compounds 3.8.1 Definition: If the number of valence electrons of the cation is sufficient to complete octahedron of the anion, the compound is called the normal valence compounds. Example: CmAn meC＝n(8－eA) sometimes: m(eC－eCC)＝n(8－eA－eAA) 3.8.2 Classification according to structure 1. NaCl and CaF2 types NaCl type: (Mg Ca Sr Ba)(Se Te) (Mn Pb Sn)(Se Te) CaF2 type: PtSn2 PtIn2 Pt2P Anti-CaF2 type: Mg2(Si Ge Sn Pb) Cu2Se Li3AlN2 LiMg(N As Sb Bi) AgMgAs 2. Diamond, Zinc blende, Wurtzite types Zinc blende: (Be Zn Ca Hg)(S Se Te) (Al Ga In)(P As Sb) Wurtzite: (Zn Cd Mn)S (Cd Mn)Se 3. NiAs structure Example: (Cr Fe Co Ni)(S Se Sb) (Fe Co)Te (Mn Fe Ni Pt Cn)Sn Ni(As Sb Bi) 3.9 Electron Phases (Hume-Rothery Phases) For example: CuZn : β e/a= (1+2)/2 = 21/14≈1.36 Cu5Zn8 : γ e/a = (5+16)/(5+8) = 21/13 ≈1.48 CuZn3 : ε(HCP) e/a = (1+6)/(1+3) = 7/4 ≈1.74 3.10 Size Factor Compounds 3.10.1 Interstitial phases (Interstitial compounds) Condition A B The atomic size of B: H (0.46), B (0.97), C (0.77), N (0.71) ? 1. Simple interstitial compound structure 2. Complex structure 1. Three