logo

您所在位置网站首页 > 海量文档  > 医药卫生 > 心理学理论/研究方法

Control of mesostructured silica particle morphology.pdf 7页

本文档一共被下载: ,您可全文免费在线阅读后下载本文档。

  • 支付并下载
  • 收藏该文档
  • 百度一下本文档
  • 修改文档简介
全屏预览

下载提示

1.本站不保证该用户上传的文档完整性,不预览、不比对内容而直接下载产生的反悔问题本站不予受理。
2.该文档所得收入(下载+内容+预览三)归上传者、原创者。
3.登录后可充值,立即自动返金币,充值渠道很便利
Control of mesostructured silica particle morphology Henry B. S. Chan,a Peter M. Budd*a and Timothy deV. Naylorb aDepartment of Chemistry, University of Manchester, Manchester, UK M13 9PL. E-mail: Peter.Budd@man.ac.uk bSmart Chemical Company Ltd., Unit 5, Blatchford Road, Horsham, W. Sussex, UK RH13 5QR Received 14th July 2000, Accepted 19th December 2000 First published as an Advance Article on the web 30th January 2001 The formation of mesostructured silica was investigated using acidic conditions with tetraethoxysilane (TEOS) as the silica precursor and cetyltrimethylammonium bromide (CTAB) as the structure directing agent. A synthesis mixture of composition 2.2TEOS : 1.1CTAB : 75HCl : 1000H2O gave a well ordered material exhibiting a range of particle shapes from extended rope-like structures of hexagonal cross-section to gyroid structures. Addition of monomethyltriethoxysilane (MTES) or tetrahydrofuran (THF) to the synthesis mixture gave rise to spherical particles. Studies of particle development showed initial growth of gel-like particles within which the mesostructure developed. A new model is proposed for the formation of mesostructured precipitates in which (1) growth of inorganic oligomers gives rise to a thermodynamically unstable mixture, (2) phase separation occurs giving droplets of a second liquid (or liquid crystal) phase rich in oligomer and surfactant, (3) the droplets are colloidally stabilized, (4) microphase separation occurs within the droplets, giving rise to a mesostructure and (5) further polymerization ?xes the mesostructure. Introduction Zeolites and other microporous materials, which have regular arrays of pores and channels with dimensions v2 nm, ?nd extensive use in catalysis and as ion exchangers and selective adsorbents. The challenge in recent years has been to extend the range of ordered nanoporous materials into the mesopore size range (2±10 nm) for application in separations and reactions involving large molecules, as chromatogra

发表评论

请自觉遵守互联网相关的政策法规,严禁发布色情、暴力、反动的言论。
用户名: 验证码: 点击我更换图片

“原创力文档”前称为“文档投稿赚钱网”,本站为“文档C2C交易模式”,即用户上传的文档直接卖给(下载)用户,本站只是中间服务平台,本站所有文档下载所得的收益归上传人(含作者)所有【成交的100%(原创)】。原创力文档是网络服务平台方,若您的权利被侵害,侵权客服QQ:3005833200 电话:19940600175 欢迎举报,上传者QQ群:784321556