原创力文档- 1、本文档共16页，可阅读全部内容。
- 2、原创力文档（book118）网站文档一经付费（服务费），不意味着购买了该文档的版权，仅供个人/单位学习、研究之用，不得用于商业用途，未经授权，严禁复制、发行、汇编、翻译或者网络传播等，侵权必究。
- 3、本站所有内容均由合作方或网友上传，本站不对文档的完整性、权威性及其观点立场正确性做任何保证或承诺！文档内容仅供研究参考，付费前请自行鉴别。如您付费，意味着您自己接受本站规则且自行承担风险，本站不退款、不进行额外附加服务；查看《如何避免下载的几个坑》。如果您已付费下载过本站文档，您可以点击 这里二次下载。
- 4、如文档侵犯商业秘密、侵犯著作权、侵犯人身权等，请点击“版权申诉”（推荐），也可以打举报电话：400-050-0827(电话支持时间：9:00-18:30)。
查看更多
Controlling_size_and_yield_of_zeolite_Y_nanocrystals_using
Controlling size and yield of zeolite Y nanocrystals using
tetramethylammonium bromide
Brett A. Holmberg, Huanting Wang, Joseph M. Norbeck, Yushan Yan *
College of Engineering––Center for Environmental Research and Technology (CE-CERT) and Department of Chemical
and Environmental Engineering, University of California, Riverside, CA 92521, USA
Received 7 October 2002; received in revised form 12 December 2002; accepted 7 January 2003
Abstract
In this study, we developed an alternative synthesis technique for the production of small colloidal zeolite Y
nanocrystals. By adding tetramethylammonium bromide as a second source of organic template, we were able to de-
couple and investigate the effect of two important synthesis parameters, tetramethylammonium concentration and
anion concentration. Optimizing these two parameters allowed us to hydrothermally synthesize highly crystalline zeolite
Y in a disperse nanocrystal form with a controllable particle size of 32–120 nm. Crystals hydrothermally synthesized
with a 1.00Al2O3–4.35SiO2–2.40(TMA)2O(2OH
)–1.2(TMA)2O(2Br)–0.048Na2O–249.00H2O (T3.6) solution com-
position were 45% smaller by volume after 54 h of crystallization at 100 C and were obtained with 73% more yield (g
zeolitic Al2O3 +SiO2/g synthesis Al2O3 + SiO2) than crystals synthesized with a 1.00Al2O3–4.35SiO2–2.40(TMA)2-
O(2OH)–0.048Na2O–249.00H2O (T2.4) composition. After 216 h, T3.6 syntheses contained 37 nm crystals with 180%
higher yield than that of T2.4 syntheses at 54 h (38 nm crystals, 0.044 g zeolitic Al2O3 + SiO2/g synthesis Al2O3 + SiO2).
The mechanisms involved in the observed crystal size decrease and yield improvement are discussed. A detailed
characterization of our zeolite Y nanocrystals is given, including powder X-ray diffraction (XRD), Fourier transform
infrared spectroscopy (FT-IR), N2 adsorption, dynamic light scattering (DLS), transmission electron microscopy
(TEM), thermogravimetric (TG) analyses, 29Si magic angle spinning nuclear magne
您可能关注的文档
- Charmless 2- and 3-body B decays and the angle alpha (phi2).pdf
- Checking Secure Interactions of Smart Card.pdf
- Chemical composition of Galactic OB stars II. The fast rotator Z Oph.pdf
- Chemical similarities between Galactic bulge and local thick disk red giant stars.pdf
- Chemo-Sensitive Running Droplet.pdf
- Chemoenzymatical grafting of acrylamide onto lignin.pdf
- China Beer Market Report 2010.pdf
- China outward foreign direct investment.pdf
- China Sporting Goods Industry Report, 2010-2011.pdf
- chinese loess and palemonsoon.pdf
文档评论（0）