Boron Nitride Porous Microbelts for Hydrogen Storage.pdf

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Boron Nitride Porous Microbelts for Hydrogen Storage.pdf

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Boron Nitride Porous Microbelts for Hydrogen Storage

WENG ET AL. VOL. 7 ’ NO. 2 ’ 1558–1565 ’ 2013 1558 January 09, 2013 C 2013 American Chemical Society Boron Nitride Porous Microbelts for Hydrogen Storage Qunhong Weng,?,?,* Xuebin Wang,? Chunyi Zhi,§,* Yoshio Bando,? and Dmitri Golberg?,?,* ?World Premier International Center for Materials Nanoarchitectonics (WPI-MANA), National Institute for Materials Science (NIMS), Namiki 1-1, Tsukuba, Ibaraki 305-0044, Japan, ?Graduate School of Pure and Applied Sciences, University of Tsukuba, Tennodai 1, Tsukuba, Ibaraki 305-0005, Japan, and §Department of Physics and Materials Science, City University of Hong Kong, Tat Chee Avenue, Kowloon, Hong Kong N anotubes (NTs) and nanosheets (NSs) are two representative low-dimen- sional nanomorphologies. Both car- bon (C) and boron nitride (BN) phases can exist in such forms. Low-dimensional BN nanomaterials are well-known for their ex- cellent chemical inertness and thermal sta- bilities.1,2 They provide excellent mechanical reinforcements and enhancement of thermal conductivity in diverse materials, such as poly- mers, ceramics, and metals.35 In the case of electrically insulating substances, low- dimensional BN nanophases are the better choice than their C counterparts due to their wide energy band gaps (～56 eV).6,7 As a hydrogen adsorbent, both experimental and theoretical studies have demonstrated that BN exhibits a higher H2 uptake capacity due to its stronger interactions with the heteropolar BN bonds and partial H2 chemisorption. 811 For example, multiwalled (MW) BNNTs with differ- ent morphologies can irreversibly adsorb 0.9 4.2 wt % of H2 at 10 MPa at room tempera- ture,8,12 far better than MWCNTs (1 wt %) at the same testing conditions.13However,～50 70% of the absorbed H2 was found to be retainedwhenH2pressurehadbeen removed. The dominating H2 adsorbing mecha- nism on C and BN surfaces at a low pressure range is physisorption, which is believed to be greatly affected by the specific surface area (SSA) and pore width o